Polyvinyl chloride polyethylene polyamine Palladium Complex of the Catalytic Heck reaction.doc

 PAGE \* MERGEFORMAT 10 Polyvinyl chloride polyethylene polyamine Palladium Complex of the Catalytic Heck reaction [Abstract] Objective: To study the load-amine polymer polyvinyl chloride - Preparation of palladium complexes and to investigate its catalytic performance. Methods: PVC as raw material, through the amination reaction of polyvinyl chloride polyethylene polyamine, and further obtained polyvinyl chloride polyethylene polyamine Palladium Complex (PVC-PP-Pd), observed in different reaction conditions iodobenzene under Heck reaction with acrylic acid catalytic properties. Results: PVC-PP-Pd in the air atmosphere can effectively catalyze the reaction of iodobenzene with acrylic acid at 100 ℃ and less amount of catalyst, may generate a higher yield of trans to replace the product, but also to facilitate recovery, reused better performance. Conclusion: PVC-PP-Pd is the Heck reaction of a good catalyst. [Keywords:] PVC Pd catalyst Heck reaction of Transition-metal catalysts for halogenated aromatic compounds and vinyl C-C coupling reaction (Heck reaction) is a three-dimensional selective formation of C-C bond of the important methods, in the drug synthesis has a wide range of applications [1]. Heck reaction catalysts most commonly used transition metal is palladium, the traditional homogeneous palladium catalyst despite high catalytic activity, but during the reaction is easy to produce palladium black, and the reaction and the reaction solution after the separation is difficult, thus affecting the Heck response to industrial applications, so developers can overcome the above-mentioned shortcomings of the supported palladium heterogeneous catalysts have important theoretical and practical significance, but also a major goal of green chemistry. Supported palladium catalyst commonly used in solid materials are generally polymer materials, carbon, amorphous SiO2, zeolites and molecular sieve, etc. [2-5]; commonly used ligand for single-tooth, high resista