Resonance light scattering of calcium in the presence of the aggregation behavior of sodium dodecyl benzene sulfonate.doc

 PAGE \* MERGEFORMAT 27 Resonance light scattering of calcium in the presence of the aggregation behavior of sodium dodecyl benzene sulfonate Of: Li Zhenquan Songxin Wang Yan Lantian Zhiming Liu Xiao Yu Zhou Haiping Wu Xia [Abstract] using resonance light scattering technique for the introduction of the probe under the conditions do not establish a direct determination at room temperature sodium dodecyl benzene sulfonate (SDBS the critical micelle concentration (CMC) method. Study found that: at room temperature , SDBS aqueous solution of the intensity of resonance light scattering (RLS with the increase of SDBS concentration increased, and when SDBS close to its critical micelle concentration, RLS intensity increased significantly, resonance light scattering peaks are at 330 and 396 nm.396 nm at RLS relationship between intensity and the concentration of SDBS curve S curve, the curve suddenly rises this point corresponding to the intersection of two tangents SDBS concentration of SDBS identified as the critical micelle concentration (CMC, which is fluorescent pyrene probe and conductivity and other methods measurement results are basically consistent. and were studied using this method the concentration of Ca2 + and SDBS SDBS octyl polyethylene glycol phenyl ether (OP aggregation behavior of the mixed system. The results show that, SDBS and OP compound in 1:3 , the enhanced ability of anti-calcium system. [Keywords:] Sodium, calcium, critical micelle concentration, light scattering, fluorescence probe, conductivity Abstract A resonance light scattering (RLS) method for the determination of critical micelle concentration (CMC) of sodium dodecyl benzene sulfonate (SDBS) was proposed. Under room temperature, the RLS intensity of the SDBS system increased with increasing SDBS concentration. And when the concentration of SDBS approached CMC, the RLS intensity had increased sharply. The RLS peaks were appeared at 330 nm and 396 nm, respectively. The plot