3结语-中南民族大学学报(自然科学版).doc

原位水热法合成介孔LaCoO3/MCF 催化剂用于CO氧化反应 李金林,龚 渺,赵福真,向 勇,韦 良, HYPERLINK javascript:ViewArticleAuthorDetail(znmzdxxbzr,201511260000002,0,0,%E5%BC%A0%E7%85%9C%E5%8D%8E,,); 张煜华 （中南民族大学 催化材料科学湖北省暨国家民委-教育部重点实验室，武汉430074） 摘 要 采用原位水热法制备了LaCoO3/MCF、LaCoO3/SBA-15催化剂，分别采用XRD、氮气物理吸附-脱附、TEM对催化剂进行了表征，并在固定床反应器中对催化剂的CO氧化反应活性进行了测试，考察了不同LaCoO3负载量和不同载体负载的催化剂的CO氧化性能. 结果表明：原位水热合成法制备的LaCoO3/MCF催化剂具有较高的比表面积(281.1~427.6 m2·g-1)和三维介孔泡沫状孔道结构，LaCoO3纳米颗粒均匀地分散在催化剂中. 催化剂的CO氧化反应活性测试表明：LaCoO3的含量显著影响催化剂的CO氧化反应活性，负载量??30%的催化剂(30LaCoO3/MCF)的反应活性最高，CO在387℃氧化完全. 与SBA-15负载的催化剂相比，催化剂30LaCoO3/MCF的催化性能明显提高. 关键词 CO 氧化反应；介孔二氧化硅泡沫；LaCoO3；原位水热法 中图分类号 TQ032；O643.36 文献标识码 A 文章编号 1672-4321( 2015) In situ Hydrothermal Synthesis of Mesoporous LaCoO3/MCF Catalysts for CO Oxidation Reaction Li Jinlin, Gong Miao, Zhao Fuzhen, Xiang Yong, Wei Liang, Zhang Yuhua (Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission Ministry of Education, Hubei Province, South-Central University for Nationalities, Wuhan 430074, China) Abstract The LaCoO3/MCF and LaCoO3/SBA-15 catalysts were prepared by in situ hydrothermally method. The catalysts were characterized by X-ray diffraction, nitrogen absorption-desorption and TEM. The oxidation reactivity of CO was tested on the fixed bed reactor and CO oxidation performance of catalyst with different LaCoO3 and carrier load was also investigated. The results showed that the LaCoO3/MCF catalysts not only had large surface area (281.1 ~ 427.6 m2·g-1) but also well-kept on mesoporous foamy channel structure. The particle sizes of LaCoO3 were uniformly dispersed in the catalyst. Tests on CO oxidation reaction activity indicated that the content of LaCoO3 had significant effect on oxidation of CO. The catalyst 30 LaCoO3/MCF with 30% load had the best activity and carbon monoxide was oxidated completely under 387℃. Compared with 30LaCoO3/SBA-15, the 30LaCoO3/MCF catalyst obtained the better catalytic properties attributed to the 3-D int