表面活性剂对ZnWO4Tb3+绿色荧光粉发光性能的影响.doc

表面活性剂对ZnWO4:Tb3+绿色荧光粉发光性能的影响 廖金生*基金项目：国家自然科学基金项目；江西省自然科学基金项目(20142BAB203004); 江西省教育厅资助项目（GJJ14410）。 作者简介：廖金生（1973－），男，副教授, 博士, 主要从事稀土发光材料的研究，E-mail:  HYPERLINK mailto:jsliao1209@126.com jsliao1209@126.com.. . 聂丽灵 王祺 钟来富 顾庆杰 （江西理工大学 冶金与化学工程学院 江西 赣州 341000） 摘要：本文采用水热法合成了应用于荧光灯的绿色荧光粉ZnWO4:Tb3+。通过采用X射线粉末衍射分析仪（XRD），扫描电子显微镜(SEM)和荧光光谱仪，系统考察了不同表面活性剂条件下合成的ZnWO4:Tb3+绿色荧光粉。结果表明，不同表面活性剂条件下，采用水热法合成的产品均为纯ZnWO4结构，Tb3+掺杂并不改变钨酸锌结构；荧光光谱仪对样品的激发和发射以及荧光衰减曲线测定表明，表面活性剂PEG-2000条件下合成的荧光粉，其发光强度增强最有效，采用PVP为表面活性剂合成ZnWO4:Tb3+的荧光粉寿命较采用PEG-2000和CTAB为表面活性剂合成的长。综合发光强度和荧光寿命的影响，选PVP为表面活性剂最佳。 关键词：水热法；ZnWO4；铽离子；发光 中图分类号: O611.4 文献标识码： A Effect of surfactant on the luminescence properties of ZnWO4: Tb3+ green phosphor LIAO Jinsheng, NIE Liling，WANG Qi，ZHONG Laifu，GU Qingjie (School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology，Ganzhou, 341000, China) Abstract： In this paper, green phosphor ZnWO4:Tb3+ applied in fluorescent lamp is prepared by a hydrothermal method. The structure, morphology and luminescent properties of ZnWO4:Tb3+ green phosphor with different surfactant are characterized by X-ray powder diffraction (XRD), Scanning electron microscopy (SEM) and Fluorescence spectrometer, respectively. It reveals that all of the as-obtained samples with different surfactants are pure ZnWO4, Tb3+ doping does not alter the structure of ZnWO4;The excitation and emission spectra as well as fluorescence decay curves of samples are measured, the results show that the use of PEG-2000 as the surfactant is the most effective for increasing fluorescent emission intensity. The luminescence life of ZnWO4:Tb3+ phosphor using PVP as the surfactant is longer than these of PEG-2000 and CTAB as surfactants. Comprehensive considering factor of emission intensity and fluorescence lifetime, using PVP as the surfactant is best choice. Key words: hydrothermal method; ZnWO4; terbium; luminescence 0 引 言 稀土离子具有丰富的能级结构，其发光波长可在紫外到红外之间变化，常被作为发光中心应用于发光材料中[ HYPERLINK \l