Solid phase extraction distributed gas chromatographyMS for the Determination of phthalates.docVIP

 PAGE \* MERGEFORMAT 14 Solid phase extraction distributed gas chromatographyMS for the Determination of phthalates Of: Zhang Dan Zhang Yu Xin-Shen Zhang Ping Yang [Abstract] established in the soil of 18 endocrine disrupters phthalates distributed microwave extraction solid phase extraction GC / MS analysis of soil samples were .10 g 20 mL methylene chloride and acetone after microwave extraction to replace the solvent acetone and concentrated to 1.5 mL. concentrated solution by adding 0.2 g C18 sorbent, shaking 3 min and centrifuged 10 min (8000 r / min), 1.0 mL supernatant obtained after replacement with hexane gas chromatography mass spectrometry analysis, and standard addition calibration curve through the matrix of phthalates compensation matrix effect. purification time of less than 20 min. purified extract of the matrix of soil removal rate of 72.7%. The linear range 7.5 ~ 750 μg / kg, the correlation coefficient greater than 0.998; 6 soil samples in the measured values #8203;#8203;of the RSD between 5.5% ~ 12.1%; measured values #8203;#8203;in soil samples spiked at 7.3% RSD between 19.4%; average recovery in between 94.4% ~ 114.6%; the detection limit was 1.2 ~ 4.3 μg / kg. [Keywords:] phthalate, distributed solid phase extraction, matrix effect, soil 1 Introduction Phthalate (Phthalate esters, PAEs) used primarily as plasticizers. The study shows that, PAEs are endocrine disruptors, carcinogenic, teratogenic and other toxic [1,2]. PAEs able to migrate into the environment , transformation, and accumulation in the soil [3]. PAEs in the soil by microwave-assisted extraction, accelerated solvent extraction, etc. were extracted. make the complexity of soil samples extract may contain a large number of interfering substances, the follow-up analysis of PAEs. Therefore, the need for purification of the extract. has been reported using solid-phase extraction [4 ~ 6] and gel permeation chromatography [7,8] and other methods to purify the soil e