With regard to Kelvin Derivation and application of the formula.docVIP

 PAGE \* MERGEFORMAT 17 With regard to Kelvin Derivation and application of the formula Abstract summed up to determine the curvature of curved surface for the liquid vapor pressure of the quantitative impact of the formula - Several Kelvin equation describes the derivation of methods and the use of Kelvin equation of some interface phenomena are explained. Keywords: Kelvin equation; additional pressure; Laplace equation Kelvin equation lnPr p = 2r M RTrρ quantitatively describe the pure liquid saturated vapor pressure and the relationship between the radius, which is the interface chemistry is an important formula. In addition to 1871 Kelvin with the derivation of methods, the derivation of this formula there are many other ways. This study summarizes the Kelvin equation is derived in several ways and introduced the use of Kelvin equation of some interface phenomena are explained. The first derivation of a method [1] With substance dn trace amount of liquid transferred from the flat surface to the radius r on the surface of the small droplets, the process shown in Figure 1. The radius of the small droplets from r to r dr, with sizes ranging from 4πr2 to 4π (r dr) 2, area increments 8πrdr, this process increases the surface Gibbs function 8πrγdr. If this process is due to dn of liquid from the vapor pressure with p flat surface pr move to have a vapor pressure of small droplets caused by the above, then the Gibbs function of the increments (dn) RTln (pr / p) . Beginning of the process of state and the two final states are the same, Gibbs function, increment equal, are: (dn) RTln Pr p = 8πrγdr (1) Because dn = 4πr2 (dr) ρ / M (2) So get ln Pr p = 2γ M RTrρ (3) Where, ρ, M, and Vm, respectively the liquid density, molar mass and molar volume. The formula shows that the smaller the droplet, the greater the saturated vapor pressure (for the concave surface, the formula in the radius of curvature can on