垃圾焚烧飞灰中CaSi对重金属Cd挥发特性的影响.pdfVIP

中国工程热物理学会 燃烧学 学术会议论文 编号：094216 垃圾焚烧飞灰中Ca/Si 对重金属Cd 挥发 特性的影响 张海军，李润东，李彦龙，田学慧，王雷 （沈阳航空工业学院辽宁省清洁能源重点实验室及清洁能源与环境工程研究所，辽宁，沈阳 110136 ） 电话 邮箱：hj_zhang@yahoo.cn 摘要：垃圾焚烧飞灰就是一种富含高浸出毒性的重金属以及高毒性当量的二噁英类化合物的危险废物， 必须进行妥善处理处置。飞灰中富含大量的钙和硅，研究 Ca/Si 对飞灰中重金属的挥发的影响具有突 出的意义。本文采用高温管式电炉研究了Ca/Si 对焚烧飞灰中重金属Cd 迁移特性的影响，并对重金属 Cd 的挥发过程进行热力学和动力学分析。研究表明，飞灰中的Cd 在高温条件下极易挥发，Ca/Si 对重 金属Cd 的挥发影响较大，最后用动态等温的方法建立了Cd 的挥发动力学模型，空气和氧气气氛下的 活化能分别为128.52KJ/mol 和133.66KJ/mol。 关键词：垃圾焚烧飞灰; 重金属; Cd; Ca/Si; 挥发 The Ca/Si Influence on Volatilization of Heavy Metal Cd in MSWI Fly Ash ZHANG Hai-jun ，LI Run-dong ， LI Yan-long ，TIAN Xue-hui ，WANG Lei (Liaoning Key Laboratory of Clean Energy and Institute of Clean Energy and Environmental Engineering, Shenyang Institute of Aeronautical Engineering, Shenyang, 110136Liaoning, China) Abstract ：Municipal solid waste incinerator (MSWI) fly ash is defined as a hazardous waste for it’s containing of high leaching ratios of heavy metals and high toxicity of dioxin, so it must be treated and disposed appropriately. Because of the high content of calcium and silicon in MSWI fly ash, so it has outstanding meaning to research the volatilization of heavy metals with Ca/Si during the thermal treatment process. In this paper, the influence of Ca/Si on volatilization of Cd in MSWI fly ash was investigated using a high-temperature tubular furnace and the volatilization process was analyzed by thermodynamics and kinetics. The result showed that, the heavy metal Cd was easily volatilized at high temperature, and the influence of Ca/Si on volatilization is very large. At last, the volat