氧化石墨烯(或石墨烯)-MnO2复合体的合成及超级电容中应用讲述.doc

氧化石墨烯(或石墨烯)-MnO2复合体的合成 及电化学性能 Synthesis and Electrochemical Performance of Graphene Oxide (or Graphene)-MnO2 Composites 大连理工大学毕业设计（论文）格式规范 氧化石墨烯/石墨烯-MnO2复合体的合成及电化学研究 -  PAGE II - -  PAGE  - 摘 要 近年来，氧化石墨烯和石墨烯以其独特的结构和优异的性能，在化学、物理和材料学界引起了广泛的研究兴趣。它们与过渡金属氧化物形成的纳米复合材料是一种很有发展前景的新型材料。 在过渡金属氧化物中，二氧化锰由于其资源广泛、价格低廉、环境友好，受到了国内外研究者的关注。用二氧化锰作为电极改性材料，首先是由于纳米二氧化锰具有很大的比表面积，其次MnO2本身也会发生氧化还原反应形成赝电容，有助于提高电容器的电容量。 本文采用改进的Hummers法对天然石墨进行氧化处理制备氧化石墨，在水溶剂或醇溶剂中经超声分散，加入KMnO4和MnCl2形成氧化石墨烯-MnO2复合材料。另一方面，将制得的氧化石墨在水合肼的作用下加热还原制备石墨烯，同样加入KMnO4和MnCl2形成石墨烯-MnO2复合材料。 实验采用三电极体系，0.5mol/L Na2SO4作为电解液，通过循环伏安、恒流充放电、交流阻抗测试，考察并讨论了溶剂种类、KMnO4和MnCl2的加入量、反应时间以及还原过程中水合肼用量等对氧化石墨烯/石墨烯-MnO2电化学性能的影响。 关键词：氧化石墨烯；石墨烯；MnO2；电化学性能 氧化石墨烯/石墨烯-MnO2复合体的合成及电化学研究 -  PAGE III - Synthesis and Electrochemical Performance of Graphene Oxide (or Graphene)-MnO2 Composites Abstract In recent years, graphene oxide and grapheme have attracted wide interest due to their unique structures and excellent performances in chemistry, physics and materials. The graphene oxide(or graphene)-metal oxide composites are new promising materials for supercapacitors. Among transition metal oxides, manganese oxide (MnO2) is paid much attention because of its natural abundance, low cost, and environmental friendliness. The use of MnO2 as the electrode material is mainly ascribed to its large surface area and pseudocapacitance. The graphite oxide was prepared from natural flake graphite by the modified Hummers method. After the ultrasonic dispersion in water solvent or alcohol solvent, the graphene oxide-MnO2 composite was synthesized by adding KMnO4 and MnCl2. The graphene was prepared by refluxing the above mentioned graphite oxide in the presence of hydrazine hydrate. And then, the graphene-MnO2 composite was prepared with the addition of KMnO4 and MnCl2. Using the three electrodes system and Na2SO4 electrolyte, the effect of solvents, amount of Mn, reaction time and amount of hydrazine hydrate on the electrochemical performance were inves