无皂种子乳液聚合制备新型增稠剂.docVIP

Material Sciences 材料科学, 2013, 3, 35-39 /10.12677/ms.2013.31007 Published Online January 2013 (/journal/ms.html) Synthesis and Charaterized of Thickener by Soap-Free and Seeded Emulsion Polymerization* Runmiao Yang, Yuhai Liu, Yaoyao Deng, Lei Huang, Yingying Qin Department of Material Engineering, Jiangsu Teachers University of Technology, Changzhou Email: yangrunmiao@ Received: Dec. 7 , 2012; revised: Dec. 24 , 2012; accepted: Dec. 29 , 2012 th th th Abstract: A kind of acrylates copolymer thickener was prepared by soap-free and seeded emulsion polymerization. In order to obtain functional polymer latex particles with clean surface and with surface carboxyl groups, Poly(sty- rene-methacrylic acid) (P(St-MAA)) seed particles with the diameter of 250 - 300 nm were synthesized via soap-free emulsion polymerization. Then the seeded emulsion copolymerization of ethylacrylate (EA), lauryl methlacrylate (LMA), St and MAA onto the seed particles were performed in the absence of emulsifier. The content of LMA effected for the particles size and the stability of the emulsion was studied. The thickening performance of this polymer latex was quite good with the high thickening performance, good suspension ability, good transparence and easy to use. The factors of the copolymerization and the properties of the emulsion were discussed. Its structure and morphology were characterize by fourier transform infrared spectrometer (FT-IR) and transmission electron microscope (TEM). Keywords: Thickener; Soap-Free and Seeded Emulsion Polymerization; Acrylic Acid; Lauryl Methlacrylate 无皂种子乳液聚合制备新型增稠剂* 杨润苗，刘玉海，邓瑶瑶，黄 磊，秦莺莺 江苏技术师范学院，材料工程学院，常州 Email: yangrunmiao@ 收稿日期：2012年 12月 7日；修回日期：2012年 12月 24日；录用日期：2012年 12月 29日 摘 要：采用无皂种子乳液聚合方法制备了一种新型丙烯酸酯共聚物增稠剂。为了获得表面清洁和表面富含羧 基的功能性聚合物乳胶粒子，首先合成了种子颗粒直径在 250~300 纳米的