丙烷无氧脱氢制丙烯工艺和催化剂的研究进展_刘乔.pdfVIP

丙烷无氧脱氢制丙烯工艺和催化剂的研究进展_刘乔.pdf

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丙烷无氧脱氢制丙烯工艺和催化剂的研究进展_刘乔

1 2 1 2 1 2 1 2 UOPOlefl exLummusCatofi n Krupp-UhdeSTARLinde-BASFLindeSnamprogettiFBD CrPtCrPt PtCr 1000 8144201406 0713 08 TQ 426.8 A 1 2 1 2 1 2 1 2 Liu Qiao Dong Xiuqin Yu Yingzhe Zhang Minhua 1. Key Laboratory for Green Chemical Technology of Ministry of EducationTianjin UniversityTianjin 300072China 2. Tianjin University R D Center of Petrochemical TechnologyTianjin 300072China Several industrialized technologies for the anaerobic dehydrogenation of propane to propylene were reviewed. Among themthe Olefl exCatofi nSTARLinde and FBD technologies were developed by UOP company Lummus company Krupp-Uhde company Linde-BASF company and Snamprogetti companyrespectively. Two kinds of common catalysts(Pt-based and Cr-based) for the anaerobic dehydrogenation were introduced. The Cr-based catalysts and relative technologies were discussed briefl y. The mechanism of the dehydrogenation over Pt-based catalysts promoters supports and preparation methods were investigated. The coking deactivation and regeneration of the two kinds of catalysts were also involved. The development trends for the propane dehydrogenation in future were presented. anaerobic dehydrogenation of propane propylene platinum-based catalysts chromium-based catalysts 2014 01 13 2014 03 05 1990 815598142@

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