各向异性的高岭石间的相互作用.doc

pH对高岭石同相凝聚及絮凝行为的影响 吴亚越1,2 廖春发1* 陈潜2 徐盛明2* （1.江西理工大学 冶金与化学工程学院 江西 赣州 341000;2.清华大学 核能与新能源技术研究院，北京 100084） 摘 要：利用带耗散因子功能的石英晶体微天平(QCM-D)研究：pHpH值的影响，在pH 8.5的情况下，高分子对高岭石吸附最紧密，而当溶液pH 6.5则形成了最为疏松的吸附层。即在弱碱性条件下，阳离子聚丙烯酰胺对高岭石的絮凝效果更好。随着溶液从弱酸性变为弱碱性，阳离子聚丙烯酰胺对高岭石的絮凝沉降速度也明显增加；沉降实验结果与QCM-D所测量的结果具有很好的一致性。 关键词：高岭石；石英晶体微天平；同相凝聚；絮凝 Effect of pH for the homoaggregationand flocculation behavior of ultrafine kaolinite Wu Ya-Yue1, 2 Liao Chun-Fa1* Chen Qian2 Xu Sheng-Ming2* School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology ,Jiangxi Ganzhou 341000, China; 2.Institute of Nuclear and New Energy Technology，Tsinghua University, Beijing 10084, China) AbstractHomoaggregation and flocculation behavior of ultrafine kaolinite in different pH aqueoussolutionwere studied by adissipative quartz crystal microbalance (QCM-D). Due to increasing the surface potential of octahedral aluminum oxy-hydroxyl (Al?O?OH), the results illustrate that homoaggregation behavior of ultrafine kaolinite were inhibited with increasing the pH value. Meanwhile, the pH of aqueous solution plays an important role in controlling the adsorption kinetics of cationicpolyacrylamide polymer on ultrafine Kaolinite.In the case of pH 8.5, polymer adsorption most closely for kaolinite, whereas when solution pH =6.5 formed the most porous adsorption layer. The cationicpolyacrylamide has better flocculation effectin alkalescence condition. As the solution from weak acid to weak alkaline, cationic polyacrylamide flocculating settling velocity of kaolinite increased significantly. The result of setting experiment consisted with the result of QCM-D. Keywords:Kaolinite; quartz crystal microbalance; homoaggregation;Flocculation 基金项目：国家自然基金面上项目 第一作者：吴亚越（1990-）E-mail：282307451@ 通讯作者：廖春发（1965-)E-mail：（1963-)E-mail： 1 引言 胶体体系在日常消费品以及生命科学中非常常见，如洗涤剂，墨水，油漆，以及血小板等。胶体在食品加工，原油开采，煤泥浮选以及空气和水污染方面也发挥了重要作用。目前针对胶体体系的稳定性及其控制胶体体系实现固液分离，如污水处理，矿物及其原油加工，造纸，制药以及精细化工等，仍然有很多重要问题有待解决[1]。 粘土是诸多工业废水中的重要组成部分，如煤泥浮选以