文章题名不超过20字黑体二号-农业环境科学学报.doc

混合无机改良剂对酸性多重金属污染土壤的改良效应 郭荣荣，黄凡，易晓媚，龙新宪*， (华南农业大学 资源环境学院、环境科学与工程系，广州市 510642) 摘 要：本研究旨在筛选适合于治理和修复酸性多金属污染土壤的无机混合改良剂。首先通过正交土壤培育实验，研究了不同剂量的石灰石、沸石和羟基磷灰石组配的混合改良剂对广东省韶关市大宝山周边的酸性多金属污染土壤的改良作用，根据其提高土壤p H和固定土壤Cu、Zn、Pb、Cd的效果，从中筛选出效果较好的六种混合改良剂配方，以红油麦菜为供试植物进行盆栽试验。土壤培育实验显示，15种混合改良剂均显著提高土壤pH，对土壤中Cu、Zn、Pb、Cd有很好的固定效果。统计分析显示，混合改良剂对土壤中Pb、Cd、Zn固化效果影响的主次为：石灰石＞羟基磷灰石＞沸石，对Cu固化效果影响主次为：石灰石＞沸石＞羟基磷灰石。盆栽试验发现：6种无机混合改良剂显著增加了土壤pH值和降低了Cd、Cu、Zn、Pb的有效态含量，且土壤pH值和Cd、Cu、Zn 的有效态含量呈显著负相关性。当土壤pH为6～7时，红油麦菜的生长健康，其中混合改良剂（沸石4 g·kg-1+2 g·kg-1石灰石 g·kg-1羟基磷灰石；Mixed Inorganic Amendments for Remediating Acidic Multi-metals Contaminated Soil GUO Rong-rong, HUANG Fan, YI Xiao-mei, LONG Xin-xian* (College of Natural Resources and Environment, South China Agricultural University, Guangzhou 510642, China) Abstract: The main objective of the present study was to determine the immobilization capacity of some mixtures of inorganic amendments to reduce the bioavailability of heavy metals in acid multiple-metals-contaminated soils. The mixtures contained different doses of limestone, zeolite and hydroxyapatite. Incubation experiment in orthogonal experimental design was conducted to study the efficiency of these mixed inorganic amendments in increasing soil pH and decreasing the mobility of Cd, Pb, Cu and Zn in an acid multi-metals-contaminated soil collected from the Dabaoshan area of Shaoguang city, Guangdong province. Then pot experiment was conducted to study the effects of six kinds of mixed inorganic amanedments on soil heavy metal bioavailabilty, on the growth and heavy metal accumulation in red leaf lettuce (Lactuca sativa L.). The soil incubation experiment showed that all the mixed inorganic amendments significantly increased soil pH and reduced the mobility of Cd, Pb, Cu and Zn. Statistic analysis showed that the ability of immobilizing soil Pb, Cd, Zn decreased as: limestone hydroxyapatite zeolite, but for soil Cu they were limestone zeolite hydroxyapatite. Pot experiment indicated that the six types of mixtu