cr00098a012 包含偶氮苯化合物的光化学反应.pdfVIP

Chem.Rev.l989,89, 1915-1925 1915 Photochemistry of Azobenzene-Containing Polymers G. SUDESH KUMAR’ Alchemie Research Centre, P.O. Box 755,Thane Belapur Road, Thane, 400 601, India D. C. NECKERS’ Center for Photochemical Sciences, Bowling Green State University, Bowling Green, Ohio 43403 Received July 27, 1988 (Revised Manuscript Received June 26, 1989) Contents more stable trans form to the less stable cis form upon I. Photochemistry of Azobenzene: Cis-Trans 1915 irradiation with UV or visible light to yield a photo- Isomerism stationary composition that is wavelength and tem- I I. Macromolecular Photochemistry 1915 perature dependent (Figure 1). Azobenzene is thus a 111. Dynamics through Kinetics: Azobenzene as a 1917 textbook representative demonstrating the rotoresistant “Probe” property of the N=N double bond,lt2 and spectros- A. Backbones: “Crankshaft-like Motion” 1917 copists and photochemists have long been aware of the 6. Side-Chain Effects 1918 inversion-rotation mechanistic dichotomy. Many the- C. Cross-Links 1919 oretical and experimental papers deal with this sub- IV. Photoresponsive Polymers: Azobenzene as a 1920 ject.3-10 “Trigger”