Corollary from the Exact Expression for Enthalpy of Vaporization英文文献资料.docVIP

HindawiPublishingCorporation JournalofThermodynamics Volume2011,ArticleID945047,7pages doi:10.1155/2011/945047 ResearchArticle CorollaryfromtheExactExpressionforEnthalpyofVaporization A.A.Sobko DepartmentofPhysicsandChemistryofNewMaterials,A.M.ProkhorovAcademyofEngineeringSciences,19PresnenskyVal, Moscow123557,Russia CorrespondenceshouldbeaddressedtoA.A.Sobko,ainrf@mail.ru Received14November2010;Revised9March2011;Accepted16March2011 AcademicEditor:K.A.Antonopoulos Copyright?2011A.A.Sobko.ThisisanopenaccessarticledistributedundertheCreativeCommonsAttributionLicense,which permitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkisproperlycited. Aproblemondetermininge?ectivevolumesforatomsandmoleculesbecomesactualduetorapidlydevelopingnanotechnologies. Inthepresentstudyanexactexpressionforenthalpyofvaporizationisobtained,fromwhichanexactexpressionisderivedfor e?ectivevolumesofatomsandmolecules,andundercertainassumptionsontheformofanatom(molecule)itispossibleto?nd theirlineardimensions.Theaccuracyisonlydeterminedbytheaccuracyofmeasurementsofthermodynamicparametersatthe criticalpoint. 1.Introduction 1938[2]withtheeditionfrom1976[3],wemay?ndthem actually similar. we may come to the same conclusion if we compare [2] with recent monograph by Prigogine and Kondepudi “Modern Thermodynamics” [4]. The chapters devotedto?rst-orderphasetransitionsinbothmonographs areidentical.Onemayassertthatforthelast60–70yearsno noticeableprogress isobservedinthetheory of?rst-order phase transitions. There is a progress in studying critical pointswhichis,however,connectedwiththefactthatata criticalpointwehaveΔV =0,ΔS=0,thatis,itbecomesthe second-ordertransition,theoryforwhich,aswasmentioned, iswelldeveloped. The heat of a transition is an important characteristic for?rst-orderphasetransitions.In1762,Black[5]wasthe ?rst who discovered that water transformation to vapor consumes some heat that he called the latent evaporation heat.ThenBlackhasconductedcalorimetri