Rationalisation of the activities of phenolic (vitamin E-type) antioxidants 外文参考文献.docVIP

Spectroscopy 17 (2003) 753–762 IOS Press 753 Rationalisation of the activities of phenolic (vitamin E-type) antioxidants Christopher J. Rhodes , Thuy T. Tran, Philip Denton and Harry Morris ? School of Pharmacy and Chemistry, Liverpool John Moores University, Byrom St., Liverpool, L3 3AF, UK Abstract. Using Transition-State Theory, experimental rate constants, determined over a range of temperatures, for reactions of vitamin E type antioxidants are analysed in terms of their enthalpies and entropies of activation. It is further shown that computational methods may be employed to calculat