活性炭改性对用于甲酸分解的Pd／活性炭催化剂的影响.pdfVIP

学兔兔 化 工 进 展 ·76· CHEMICAL INDUSTRYAND ENGINEERING PROGRESS 2010年第29卷第1期 活性炭改性对用于甲酸分解的Pd／活性炭催化剂的影响 方向红 -一，张寅秋 ，崔 鹏。 ( 安徽职业技术学院化工系，安徽 合肥 230051； 合肥工业大学化学工程学院，安徽 合肥 230009) 摘 要：采用磁力搅拌法和水浴振荡法制备应用于甲酸分解的Pd／活性炭(AC)催化剂，研究了活性炭载体改性 和制备方法对催化剂分解甲酸性能的影响。采用恒温水浴振荡装置，在80~C水浴中进行甲酸催化分解反应，以甲 酸的催化分解率评价催化剂催化活性。结果表明，以经过不同的酸、碱、盐溶液改性后的活性炭为载体采用不同 方法制备的Pd／AC催化剂对甲酸的催化分解效果不同，以Na2CO3改性的活性炭为载体采用磁力搅拌法制备的催 化剂活性最好，甲酸水溶液的分解率达85％；X上，含甲酸的工业废水的分解率达70％。 关键词：活性炭；改性；Pd／活性炭催化剂；甲酸分解 中图分类号：TO 032 文献标识码：A 文章编号：1000—6613(2010)01—0076—04 Effect of activated carbon modification on Pd／activated carbon catalyst for decomposition of formic acid solution FANGXianghong ，ZHANG Hnqiu2，CUIPengz ( Anhui Vocational and Technical College，Hefei 23005 1，Anhui，China： School ofChemical Engineering，Hefei University of Technology，Hefei 230009，Anhui，China) Abstract：Electromagnetic stirring and oscillation bath were used to prepare Pd／(activated carbon) catalyst for the decomposition of formic acid，and the effects of activated carbon modification and preparation methods to catalytic activity were investigated．Using thermostatic water oscillation device， the activity of catalyst was evaluated at 80℃ by the rate of formic acid decomposition．Results showed that P(1／AC catalysts prepared from activated carbon modified with different acid，alkali and salt solutions have different activity for the decomposition of formic acid．Pd／AC catalyst prepared from activated carbon modified with NazCO3 solution under electromagnetic stirring shows the highest catalytic activity with decomposition of