活性炭纤维吸附处理模拟焦化废水尾水.pdfVIP

学兔兔 化 工 进 展 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2012年第3 1卷第12期 活性炭纤维吸附处理模拟焦化废水尾水 张 培 ，张小平 ，兰永辉2，韦朝海 ( 华南理工大学环境科学与工程学院，工业聚集区污染控制与生态修复教育部重点实验室，广东广州510006 东江环保股份有限公司，广东 深圳 518057) 摘 要：采用活性炭纤维静态吸附苯酚模拟焦化废水尾水，考察了活性炭纤维用量、温度、pH值、无机物、有 机物等因素对处理效果的影响，从化学性质和热力学数据等方面来判断吸附类型。结果表明，活性炭纤维对苯 酚的吸附容量最大为107．11mg／g，吸附效果随温度升高有所下降，溶液pH5时不利于吸附的进行，多组分的存 在抑制苯酚的吸附。热力学参数△ 、△Go为负值，表明该吸附是一个自发的放热过程。 关键词：活性炭纤维；苯酚；热力学 中图分类号：x 52 文献标志码：A 文章编号：1000—6613(2012)12—2786—05 Adsorption and treatment of simulated coking waste water by activated carbon fiber ZHANGPei ，ZHANGXiaoping ，LANYonghui ，WEIChaohai ( The Key Lab of Pollution Control and Ecosystem Restoration in Industry Clusters，College of Environmental Science and Engineering，South China University ofTechnology，Guangzhou 510006，Guangdong，China； Dongjiang Environmental Co．Ltd．，Shenzhen 5 1 8057，Guangdong，China) Abstract：The adsorption of phenol from simulated coking water on activated carbon fiber(ACF)was studied．The chemical and thermodynamics factors affecting adsorption，such as ACF does，temperature， pH，inorganic substances，organi。c compound were investigated．The results showed that phenol adsorption capacity on ACF was 1 07．1 1 mg／g and adsorption efficiency decreased with an increase of temperature．ACF was adsorbed well when pH5 and the presence of inorganic and organic substances inhibited the sorption efficiency．Both△ and AG”were negative．SO the adsorption was considered as spontaneous