活性碳纤维低温选择性催化还原NO的机理研究进展.pdfVIP

学兔兔 化 工 进 展 ·1478· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 201 1年第30卷第7期 活性碳纤维低温选择性催化还原NO的机理研究进展 黄 华 存 (河池学院化学与生命科学系，广西 宣州546300) 摘 要：简述了不同反应物组合在碳材料表面的行为特征，单组分NO可以形成吸附态的NO2、二聚体(N0)2、 -- NO2或吡啶类的化合物；O2存在时NO被吸附态的氧氧化成NO2；NO、O2和NH3同时存在时，反应发生在 吸附态的NH 和吸附态的NO2之间。着重详述了活性碳纤维(activated carbonfibers，ACF)催化剂上的选择性 催化还原 (selective catalytic reduction，SCR)NO的机理为：低温时以NH 为还原剂的SCR(NH3-SCR)遵循 Langmuir—Hinshelwood机理，较高温度时NH 一SCR遵循Eley—Rideal机理；分析指出了催化剂孔结构特征和表面 化学官能团是ACF能低温选择性催化还原NO的主要影响因素。 关键词：碳材料；活性碳纤维；反应机理；选择性催化还原 中图分类号：TQ426 文献标志码：A 文章编号：1000—6613(2011)07—1478—05 Research advance in mechanism of low—temperature SCR of NO on carbon materials HUANG Huacun (Department of Chemistry and Life Science，Hechi College，Yizhou 546300，Guangxi，China) Abstract：The behavior of the reactant molecules on carbon materials surface，formation of adsor~Ied NO2，dimer(NO)2，一No2 or pyridine compounds from single component NO is reviewed．When N0 and O， coexists，NO is oxidized to NO2 by the adsorbed O2．When NO，O2 and NH3 coexists，the reaction occurs between adsorbed NH and adsorbed NO，．The mechanism of selective catalytic reduction(SCR)of NO on activated carbon fibers(ACF)catalyst is presented as follows．At a low temperature NH3-SCR follows the Langmuir-Hinshelwood mechanism．While at a high temperature NH 一SCR follows the Eley．Rideal mechanism．The catalyst pore structure characteristics and surface chemical functional groups are the main factors of the low temperature SCR of N0． Key words：carbon material；activated carbon fiber；reaction mec