Hβ催化剂上乙醇制丙烯.pdfVIP

学兔兔 石 油 化 工 · 386· PETROCHEMICAL TECHNOL0GY 2014年第43卷第4期 Znml~催化剂上乙醇制丙烯 程 杰，王 峰，张 莉，张贵泉，白 婷，张 昕 (西北大学 化工学院，陕西 西安 710069) [摘要]优选硅铝比为25的Hp分子筛，以不同种类的Zn盐为前体，采用浸渍法对Hp分子筛进行改性，制备了不同zn负载量的 Zn／H[3催化剂，并用于乙醇制丙烯反应。考察了zn负载量、前体zn盐种类和反应条件对该催化剂上乙醇制丙烯反应性能的影 响。应用XRD、TEM、FTIR、N2等温吸附一脱附和NH 一TPD等方法对催化剂进行了表征。实验结果表明，Zn／H[3催化剂上zn 负载量和前体zn盐种类影响催化剂的织构性质和酸性，进而影响其活性。在500℃、0．1 MPa、乙醇分压23 kPa、重时空速 2．8 h。。的条件下，~ZnC1，为前体、zn负载量为16％(W)的16％Zn／HI3一C催化剂上的丙烯收率最高(43．4％)，这主要归结于该催 化剂具有适宜的酸量、酸分布和孔道结构。 [关键词]乙醇；丙烯；锌／hi3分子筛催化剂 [文章编号]1000—8144(2014)04—0386—08 [中图分类号]TQ 221．212 [文献标志码]A Conversion of Ethanol to Propylene over ZIl／II Catalysts ChengJie，Wang Feng，ZhangLi，Zhang Guiquan，Bai Ting，ZhangXin (School ofChemical Engineering，No~hwest University，Xi’an Shaanxi 710069，China) [Abstract]Zn／H~catalysts with different Zn—loading were prepared from HD zeolite with the silica- alumina ratio of 25 by an impregnation method and used in the conversion of ethanol to propylene．The effects of Zn—loading，zinc salt precursors and reaction conditions on the activities of these catalysts were investigated．The physicochemical properties of these catalysts were characterized by means of XRD，TEM，FTIR，N2 isothermal adsorption—desorption and NH3-TPD．The results showed that， the Zn-loading and zinc salt precursors had evident effect on the texture properties and the acidity of these Zn／HI3 catalysts．which affected the catalyst activity．The propylene yield was the highest 43．4％ under the optimal conditions of 1 6％(w)Zn