LDPE-EVA共混材料的力学性能及热性能.pdfVIP

学兔兔 化 工 进 展 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2011年第30卷第9期 木质素／LDPE EVA共混材料的力学性能及热性能 周 建，罗学刚 (西南科技大学，生物质材料教育部工程研究中心，四川1绵阳 621010) 摘 要：以天然热塑材料木质素和LDPE—EVA为原料，研究了不同木质素以及增容剂含量对木质素／LDPE—EVA 共混材料的力学及热性能影响。结果表明，20份木质素与LDPE—EVA共混效果较好，拉伸强度达到最大(25．88 MPa)，较LDPE—EVA聚合物提高了9％，且共混物在100℃附近的吸热峰出现一定左移(3．6℃)，降解性能增 加；10份增容剂LDPE—g—MAH的加入使体系拉伸强度达到35．66MPa，较未加增容剂时提高了26．6％，100C附 近的吸热峰进一步左移 (2℃)，降解性能小幅降低，显著提高了共混物的相容性。 关键词：木质素；LDPE—EVA；力学性能；热性能 中图分类号：TQ 321．5 文献标志码：A 文章编号：1000—6613(2011)09—2026—05 Mechanical and thermal properties of Iignin／LDPE-EVA blends ZHOU Jian，LUO Xuegang (Engineering Research Center of Biomass Materials，Ministry of Education，Southwest University of Science and Technology，Mianyang 621010，Sichuan，China) Abstract：The mechanical and thermal properties of lignin／LDPE—EVA blends were investigated with different offers of lignin and compatibilizer．The results indicated that the tensile strength of blends was increased to 25．88MPa(increase by 9％compared to the LDPE—EVA)and the decrease of endothermic peak and improvement of degradation were observed with filling 20 parts of lignin．In addition，the introduction of 1 0 parts of compatibilizer LDPE—g—MAH was the main reason for the continued increase of strength tensile and decrease of endothermic peak，which improved the compatibility of blends． Key words：lignin；LDPE—EVA；mechanical properties；therm al properties 木质素(1ignin)与纤维素和半纤维素是构成植 开裂性能，且挠曲性和韧性也很好。将PE和EVA 物骨架的主要成分，来源十分丰富。据估计，每年 共混，可制成具有较好印刷性和黏结性，且柔韧性、 全世界由植物生长可产生150