Al_2O_3-ZrO_2负载Ni_2P催化剂加氢脱硫脱氮活性.pdfVIP

学兔兔 化 工 进 展 2012年第3l卷第5期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·1047· Al2O3．ZrO2负载Ni2P催化剂加氢脱硫脱氮活性 李 锋 ，宋 华 ，张华阳 ( 东北石油大学化学化工学院，石油与天然气化工省重点实验室，黑龙江 大庆 163318； 中国石油大庆石化公司炼油厂，黑龙江 大庆 16371 1) 摘 要：采用浸渍一沉淀法制备A12O3．ZrO2复合氧化物，通过程序升温还原法制备Ni2P／A12O3．ZrO2催化剂。运用 x射线衍射、N2吸附一脱附、x射线光电子能谱技术对载体和催化剂进行表征，并以噻吩加氢脱硫、吡啶加氢脱 氮反应为探针考察复合氧化物对Ni2P催化剂加氢活性的影响。结果表明，在A12O3表面引入少量ZrO2，既保持 了丫-A12O3大比表面积的结构优势，又减少了P或Ni与Al2O3表面的接触，促进Ni2P的形成 载体中ZrO2质量 分数20％的Ni2P／A12O3一ZrO2催化剂活性最高，载体焙烧温度过高会导致催化剂活性下降。 关键词：AI2O3．ZrO2；复合氧化物；Ni2P；加氢脱硫；加氢脱氮 中图分类号：O 643 文献标志码：A 文章编号：1000—6613(2012)05—1047—05 Study on the hydrodesulfurization and the hydr0 IenitrOgenati0n over AI203-ZrO2 supported Ni2P catalysts LIFeng ，SONGHua ，ZHANGHuayang2 ( College of Chemistry and Chemical Engineering Department，Provincial Key Laboratory of Oil and Gas Chemical Technology，Northeast Petroleum University，Daqing 163318，Heilongiiang，China； Refinery ofCNPC Daqing Petrochemical，Daqing 16371 1，Heilongjiang，China) Abstract：A series ofA1203-ZrO2 composite oxides were prepared by impregnation-deposition method． Ni2P／A1203·-ZrO2 catalysts were prepared by temperature--programmed reduction in a HE flOW．The supports and catalysts were characterized by X-ray diffraction(XRD)，N2 adsorption-desorption and X—ray photoelectron spectroscopy(XPS)．The effect of composite oxides on the performance of Ni2P catalysts was studied by thiophene hydrodesulfurization and pyridine hydrodeni仃ogenation．The results showed that the introduction of small amounts of ZrO2 on the surface of A1203 woul