Shell干煤粉气化的模拟与分析.pdfVIP

学兔兔 化 工 进 展 2014年第33卷增刊 1 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·145· ^ p 4 4 4 q4—口 {研究开发2 i—： 1 —； — 1— ； Shell干煤粉气化的模拟与分析 刘建峰 ，邓蜀平 ，蒋云峰 ，刘永 ( 中国科学院山西煤炭化学研究所，山西 太原 030001； 中国科学院大学，北京 100049) 摘 要：为研究Shell干煤粉气化特点，利用Aspen Plus模拟软件为工具，建立Shell气化炉模型。通过模拟Shell 干煤粉气化的压力、氧煤比、蒸汽煤比对气化过程的影响，结果表明，增加压力能够使合成气中的甲烷含量升 高，氧煤比和蒸汽煤比对气化温度和合成气组成有重要影响。气化温度随氧煤比的增加而升高，有效气体摩尔分 数先增加后减少，蒸汽煤比可以调节气化反应温度。对屯留煤来说，Shei1煤气化的最佳氧煤比为0．74～0．80kg／ kg，反应温度为 1475．6～1580．17~C，最佳蒸汽煤比为 0．09～0．13kg／kg，相对应的反应温度为 1630．60～ 1532．11℃。 关键词：Aspen Plus；煤气化；Shell气化炉；模拟 Simulation and analysis of dry pulverized coal gasification in Shell gasifier LJ己，Jianfeng ～，DENG Shuping ，JIANG Yunfeng ，L 己，Yong ( Institute of Coal Chemistry，Chinese Academy of Sciences，Taiyuan 030001，Shanxi，China； 。University of Chinese Academy of Sciences，Beijing 100049，China) Abstract：To study the pulverized coal gasification performance of Shell gasifier，a gasifier model was established by taking Aspen Plus as the simulation too1．The effects of pressure，oxygen to coal ratio and steam to coal ratio on the gasification process were studied．Methane in the syngas increased with increasing pressure。and oxygen—coal ratio and steam—coal ratio had an important influence on operation temperature and components of the syngas．With increasing oxygen—coal ratio gasification temperature increased，mole fraction of effective gases increased first and then decreased．Steam—coal ratio could adj ust gasification temperature．Optimal oxygen—coal ratio and steam—coal ratio for Tunliu coal gasification in Shell gasifier were 0．74一O．8kg／kg and 0．09— 0．13kg／kg respectively，