Fenton试剂协同预涂动态膜处理乳化油废水.pdfVIP

学兔兔 化 工 进 展 ·942· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 20 1 3年第32卷第4期 Fenton试剂协同预涂动态膜处理乳化油废水 杨 涛，李国朝，杨期勇，曾湘晖 (九江学院化学与环境工程学院，江西 九江 332005) 摘 要：为减低预涂动态膜处理乳化油废水过程中的在线膜污染阻力，对Fenton试剂协同高岭土预涂动态膜处 理乳化油废水特性进行了研究，考察了Fe2+／H2O2配比、溶液pH值及操作温度对减缓膜污染程度的影响。研究 结果表明：投加 Fenton试剂可明显地降低在线膜污染阻力，有效去除溶液及动态膜表面的污染物，c_H’O^／ 。SO4 最佳配比为1，其稳态膜通量是未投加Fenton试剂的3倍以上；Fenton试剂在酸性条件下减缓膜污染的效果较 好，其中pH值为3时的稳态膜通量最高；最佳_T-艺操作温度为312 K，温度过高时尽管初始膜通量非常高，但 稳态膜通量较低；原料液中油浓度越高，Fenton试剂对在线膜污染阻力的削减程度越小，投加和未投加 Fenton 试剂时达到稳态时的截留率相差在l％以内。 关键词：动态膜；膜污染；Fenton试剂；氧化 中图分类号：X 703．1；TQ 028．8 文献标志码：A 文章编号：1000—6613(2013)04—0942—05 DoI：10．3969／j．issn．1000—6613．2013．04．037 A coupling process of pre-coating dynamic membrane with Fenton reagent for treatment of oily wastewater YANG Tao，LI Guochao，YANG Qiyong，ZENGXianghui (School ofChemistry and Enviromem Engineering，Jiujiang University，Jiujiang 332005，Jiangxi，China) Abstract：In 0rder to reduce the on-line membrane fouling resistances of the precoated dynamic membrane treating the emulsified oil wastewater，a coupling process of precoated dynamic membrane with Fenton reagent for treatment of oily wastewater was studied．Impacts of Fe ／H202 ratios，pH values and operation temperatures on membrane fouling degree were investigated．The results showed that the addition of Fenton reagent obviously reduced the on—line membrane fouling resistances and removed the contaminants from the solution and surface of dynamic membrane．The optimal ratio of