Ti／nanoTiO2．PAn复合膜电极催化降解甲基橙.pdfVIP

学兔兔 化 工 进 展 ·2554· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 201 1年第30卷第1 1期 Ti／nanoTiO2．PAn复合膜电极催化降解甲基橙 徐 迈，王凤武，胡云虎，方文彦，朱传高 (淮南师范学院化学与化工系，安徽 淮南 232001) 摘 要：利用溶胶．凝胶法和电化学聚合制得TYnanoTiO2 PAn复合膜电极，并通过x射线衍射仪(XRD)、扫描 电子显微镜(SEM)及循环伏安法(CV)对制备的Ti／nanoTiO2一PAn复合膜电极的结构、表面形貌和性能进行了 表征。以此电极对偶氮染料甲基橙进行了催化降解处理，研究了初始浓度、不同电极等因素对甲基橙电催化氧 化降解的影响，结果表明Ti／nanoTiO2一PAn复合膜电极对甲基橙具有较高的电催化氧化活性，其电催化活性优于 Ti／nanoTiO2电极。 关键词：复合膜；电极；电催化；降解；甲基橙 中图分类号：O 643．3 文献标志码：A 文章编号：1000—6613(2011)11—2554—04 Investigation on the electr0cata lytic degradation of methyl orange on Ti／nanoTiO2-PAn electrode XUMai，WANGFengwu，HUYunhu，FANG Wenyan，ZHUChuangao (Department of ChemisⅡy and Chemical Engineering，Huainan Normal College，Huainan 232001，Anhui，China) Abstract：Polymerization of aniline on a nanoTiO2 complex film electrode was achieved by sol—gel method and electrochemical polymerization technique．XRD，SEM and CV were used to characterize the structure and image of the nanoTiO2一PAn complex film．The nanoTi02一PAn complex film electrode was used to process the electrocatalytic degradation of methyl orange．By using the nano ZiO2一PAn composite film as electrode，effects of initial concentrations，different electrodes and other factors on the electrooxidation degradation of methyl orange were investigated．The Ti／nanoTiO2一PAn complex film electrode shows a high electrocatalytic oxidation activity in dealing with organic wastewater．The electrocatalytic activity of Ti／nanoTiO2一PAn complex film electrode is better than that of Ti／nanoTiO2 electrode． Key words：comple