TiO_2纳米管阵列膜光催化降解苯胺.pdfVIP

学兔兔 化 工 进 展 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2012年第31卷第3期 TiO2纳米管阵列膜光催化降解苯胺 李晓东 2，朱元成 。，潘素娟 ～，王长青 ( 天水师范学院新型分子材料设计与功能重点实验室，甘肃 天水 741001； 天水师范学院生命科学与化学学院，甘肃 天水 741001) 摘 要：利用TiO2纳米管阵列光催化降解含苯胺水样，考察了影响苯胺降解率的各种因素。结果表明，在照射 光源波长254 nln，反应时间120 rain和苯胺水溶液pH：9时，TiO2纳米管阵列光催化氧化苯胺的效果最好，苯胺 降解率达到87％；另外在苯胺水样中加入含Fe3+、cu 的金属盐和少量的H202氧化剂后，对TiO2纳米管阵列的 催化活性具有促进作用，其苯胺降解率分别提高了42％、31％和19％。探讨了TiO2纳米管阵列光催化降解苯胺 的反应机理。 关键词：TiO2纳米管阵列；光催化氧化；苯胺；降解率 中图分类号：TQ 426．8 文献标志码：A 文章编号：1000—6613(2012)03—0558—05 Ph0t0catalytic degradation aniline by TiO2 nanotube arrays film LIXiaodong 2 ， ZHU Yuancheng ～，PANSujuan ～，WANG Changqing ’ ( Key Laboratory for New Molecule Material Design and Function ofGansu，Tianshui 741001，Gansu，China： College ofLife Science and Chemistry，Tianshui Normal University，Tianshui 741001，Gansu，China) Abstract：In this paper，the Ti02 nanotube arrays were successfully applied to photocatalytic degradation aniline．The factors that influence photocatalytic degradation aniline were also investigated．The results showed that the optimal reaction condition is UV wavelength irradiation of 254 am，reaction time of 120 min and pH of9，under which the ratio ofdegradation ofaniline reached 87％．Furthermore，the TiO2 nanotube arrays’photocatalytic degradation activity was improved validly when Fe”，Cu and H2O，oxides were added into the reaction system，and the degradation rate was improved by 42％，3 1％ and 19％．Possible mechanisms for photocatalytic degradation aniline with TiO，nanotube