无烟煤化学链燃烧过程燃料氮转化释放特性.pdfVIP

学兔兔 化 工 进 展 2016年第35卷第1期 CHEMICAL 1NDUSTRYAND ENGINEERING PROGRESS ·327· 无烟煤化学链燃烧过程燃料氮转化释放特性 郭万军，张海峰，宋涛，沈来宏 (能源热转换及其过程测控教育部重点实验室，东南大学能源与环境学院，江苏 南京210096) 摘要：基于赤铁矿石载氧体，在小型单流化床反应器上，开展煤挥发分和焦炭的化学链燃烧研究，探讨挥发分 氮和焦氮在化学链燃烧过程中的转化特性。研究表明：燃料氮释放的中间产物HCN和NH 与铁矿石载氧体具有 较高的化学反应亲和性，易于被载氧体氧化生成N2和NO。淮北无烟煤挥发分氮转化过程中，NO是唯一的氮氧 化物，反应器出口中间产物NH3的释放份额略高于HCN。在煤焦化学链燃烧还原过程中，部分燃料氮释放的中 间产物HCN和NH3被铁矿石氧化导致少量NO的生成，还原过程中无N2O的释放·9较高的还原反应温度加速 了NO的生成。减少进入载氧体氧化再生过程的焦炭量可减少空气反应器NO和N，O的生成。 关键词：化学链燃烧；煤；燃料氮；转化特性 中图分类号：TQ534．9 文献标志码：A 文章编号：1000—6613(2016)01—0327—09 DoI：10．16085~．issn．1000—6613．2016．01．045 Fuel nitrogen transfer in chemical looping combustion of anthracite GUO Wanjun，ZHANGHaifeng，SONG Tao，SHENLaihong (Key Laboratory for Energy Heat Transfer and its Process Control ofMinistry ofEducation，School ofEnergy and Environment，Southeast University，Nanjing 210096，Jiangsu，China) Abstract：The present paper presents the investigation of fuel nitrogen transfer of anthracite in chemical looping combustion(CLC)with an iron ore oxygen carrier based on a small scale fluidized bed reactor~With respect to its volatile nitrogen and char nitrogen conversion behavior，the combustion characteristics of volatile matter and its corresponding char were experimentally investigated．The nitrogen intermediates(HCN and NH3)from fuel nitrogen had a high chemical affinity with the bed materials of the iron ore oxygen carrier towards formation of N2 and NO．During the volatile nitrogen conversion of the Huaibei anthracite，NO was the sole product of nitrogen oxide．Meanwhile，some HCN and NH3 were released and