利用壳聚糖的生产废弃液制备双乙酸钠.pdfVIP

学兔兔 化 工 进 展 ·908· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2009年第28卷第5期 利用壳聚糖的生产废弃液制备双乙酸钠 周统武 ，蔡 娟 ( 茂名学院，广东 茂名525000； 南京工业大学理学院，江苏 南京 210009) 摘 要：工业上用甲壳素生产壳聚糖会产生高浓度强碱性废液，传统工业方法是将其处理后排放，这样既浪费资 源又污染环境。本丈利用该废液制备防腐剂— R乙酸钠 (SDA)，从废液脱色、浓缩、投入乙酸的量、反应温度、 反应时间、干燥温度与时间等制备条件进行了研究，确定了最佳制备工艺。所得产品中含40．38％乙酸和58．42％ 乙酸钠，水含量小于2％，质量符合FAO／WHO标准。 关键词：壳聚糖；脱乙酰基废液；双乙酸钠 中图分类号：TQ 225．12 2 文献标识码：A 文章编号：1000—6613(2009)05—0908—03 Preparation of sodium diacetate with waste liquid produced in making chitosan from chitin ZHOUTongwu 2 ， CAIJuan f Maoming College，Maoming 525000，Guangdong，China； College of Science，Nanjing University ofTechnology， Nanjing 210009，Jiangsu，China) Abstract：The high concentration of alkaline waste liquid is generated from chitin when lt IS used for preparing chitosan．In traditional production the alkaline waste liquid is discharged，causing waste and pollution．The alkaline waste liquid can be used for the production of a preservative，sodium diacetate (SDA)．This papre studied discoloring and enriching the liquid，addition of acetic acid，reaction temperature，reaction time，drying temperature and drying time．The optimum preparation conditions were determined．Percentage contents of acetic acid，sodium acetate and water in the product were 40_38，58．42 and2 respectively by using the technology．They met the quality specification of FAO／WHO． Key words：chitosan；deacetylate waste liguid；SDA 工业上壳聚糖是由甲壳素在高浓度强碱性介质