手性Gemini表面活性剂的研究进展.pdfVIP

学兔兔 化 工 进 展 2013年第32卷第7期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·1 649· 手性Gemini表面活性剂的研究进展 梁亚琴 ，胡志勇 ，曹端林 ，梁 栋 ( 中北大学化工与环境学院，山西 太原 030051； 长治学院化学系，山西 长治 046011) 摘 要：回顾了近年来手性Gemini表面活性剂的合成和应用研究进展，按照天然手性源种类对其进行归纳和总 结，阐述了酒石酸基、氨基酸基、糖基和松香基等手性Gemini表面活性剂合成方法的研究现状，并介绍了手性 Gemini表面活性剂具有高表面活性、生物相容性、可生物降解性和立体选择性等特点。最后，指出了手性碳原 子的立体构型对于手性Gemini表面活性剂自组装行为的影响还有待于进一步研究，展望了其在制备手性介孔材 料、药物载体和胶束催化等领域的发展趋势。 关键词：手性表面活性剂；Gemini；合成；胶束 中图分类号：TQ 423．12 文献标志码：A 文章编号：1000—6613(2013)07—1649—08 DoI：10．3969~．issn．1000-6613．2013．07．033 Progress of synthesis and application of chiral Gemini surfactants LIANG Yaqing 2 HUZhiyong ，CAODuanlin ，LIANGDong ， ( School ofChemical Engineering and Environment，North University ofChina，Taiyuan 030051，Shanxi，China Department ofChemistry，Changzhi College，Changzhi 04601 1，Shanxi，China) Abstract：Research progress of synthesis and application of chiral Gemini surfactants was reviewed． According to the kind of chiral resourse，advances in the synthesis of chiral Gemini surfactants derived from tartaric acids，amino acids，alkyl glucosides and rosins were summarized．The properties of chiral Gemini surfactants were introduced，such as high surface activity，biocompatibility，biodegradability and stereoselectivity．Then，the effects of chiral carbon atoms on self-assembling of chiral Gemini surfactant which needed to be investigated further were presented．The prospects for its applications in chiral mesoporous material，drug carrier and micellar catalysis were also proposed． Key words：chiral su