氯乙烯生产技术.pdfVIP

学兔兔 化 工 进 展 ·3164· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2014年第33卷第12期 氯乙烯生产技术 张晶。段明哲，张志刚，张栋博 (陕西煤业化工技术研究院有限责任公司，陕西 西安 710065) 摘要：从氯乙烯 (VCM)传统工艺和新工艺的研究热点着手，介绍了氯乙烯生产工艺。发现传统工艺包括电石 乙炔法、乙烯法、乙烷法研究集中于关键催化剂的研究，电石乙炔法中无汞催化剂开发尚不成熟，其研究进展 将制约电石乙炔法前景，乙烯法关键催化剂尚未实现国产化，乙烷法催化剂研究尚不成熟且难度较大。乙炔二 氯乙烷重整催化法是正处于开发阶段的新-5-艺，尚需进一步论证且经工业化示范后方可实现工业应用，该技术 过程清洁、成本较低，是一条符合我国国情的有发展前景的．Y-艺。 关键词：石油；生产；聚合物；氯乙烯；二氯乙烷 中图分类号：TQ 325．3 文献标志码：A 文章编号：1000—6613(2014)12—3l64—06 DoI：10．3969q。issn．1000—6613．2014．12．006 Vinyl chloride monomer production technology ZHANGJing，DUANMingzhe，ZHANG Zhigang，ZHANG Dongbo (Shaanxi Coal and Chemical Technology Institute Co．，Ltd．，Xi’an 710065，Shaanxi，China) Abstract：Viny1 chloride monomer(VCM)production processes iS analyzed based on research status of traditional production and new production．Research of traditional production，including carbide acetylene method，ethylene method and ethane．based method iS focused on catalysts．Mercury—free catalyst of carbide acet3rlene method iS not matured at the monent，and its research status determines the progress of the carbide acetylene method．Catalyst of the ethylene method is not localized．Catalyst of the ethane．based method is not matured and its development is difficult．Catalytic reforming of acetylene and ethylene dichloride method was at development stage，and would be matured processes only through further improvement and industrial demonstration．It was a clean，lowcost method，and would be a promising methOd that suits Chinese act