活性炭液相吸附脱除二甲基二硫醚.pdfVIP

学兔兔 化 工 进 展 2012年第31卷第6期 CHEMICAL 1NDUSTRY AND ENGINEERING PROGRESS ·1357· 活性炭液相吸附脱除二甲基二硫醚 曹国强，郑辉东，邹文虎，王碧玉 (福州大学化学化工学院，福建 福州 350108) 摘 要：通过椰壳活性炭对模拟硫酸盐松节油进行液相吸附脱硫的研究，考察了活性炭的结构和表面化学对活 性炭吸附的影响。通过Gaussian03计算模拟油中各化合物的化学硬度，根据软硬酸碱理论解释表面化学对该吸 附过程的影响。同时考察了活性炭吸附过程的热力学性质。结果表明，由于吸附体系中的二甲基二硫醚和莰烯 的化学硬度相接近，活性炭表面的含氧官能团的变化对吸附性能影响不大，但活性炭比表面积和孔结构的变化 对吸附性能的影响较为明显；等温吸附平衡数据符合Freundlich等温吸附模型，热力学数据显示该活性炭吸附过 程是一个放热、混乱度降低的自发物理吸附过程。 关键词：活性炭；吸附；表面化学；吸附热力学；二甲基二硫醚 中图分类号：TQ 914．3 文献标志码：A 文章编号：1000—6613(2012)06—1357—06 Removal of dimethyl disulfide compounds from sulfate turpentine by activated carbon adsorption CAO Guoqiang，ZHENG Huidong，ZOU Wenhu，WANGBiyu (College ofChemistry and Chemical Engineering，Fuzhou University，Fuzhou 350108，Fujian，China) Abstract：Activated carbons of coconut shell were tested as adsorbents of removing dimethyl disulfide and the effects of surface chemistry and pore structure on the adsorptions were investigated．Chemical hardness was computed to interpret the effect of surface chemistry on the adsorptions by Hard and Soft Acids and Bases (HSAB) theory．Moreover the thermodynamic property of the adsorptions was studied．The results show that the number of acid oxygen functional groups has little influence on the adsorptions due to the similar chemical hardness among compounds in sulfate turpentine．However specific surface area and pore volume have great impact on the adsorption．The adsorption isotherm s of dimethyl disulfide on the activated carbons fit the Freundlich model and equation satisfactorily．And