滴流床反应器上α-甲基苯乙烯加氢影响因素分析.pdfVIP

学兔兔 化 工 进 展 2012年第31卷第5期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·l173· 滴流床反应器上 甲基苯乙烯加氢影响因素分析 丁 恒 阳 (北京燕山石油化工股份有限公司化工三厂，北京 102500) 摘 要：以 ．甲基苯乙烯、氢气为原料在滴流床反应器中催化加氢合成异丙苯。本文主要考察反应温度、压力、 循环量及进料a．MS的浓度、氢油比、催化剂、床层设计等因素对加氢反应的影响。结果表明，反应温度提高只 在60～120℃范围内能够加快反应速率；压力在0 7～0．8 MPa时加氢反应速率最快，处理能力最大；氢油比的 提高在保证原料与催化剂接触时间的前提下对反应有利；循环量及进料a．MS的浓度可以改变反应速率但是不能 改变实际处理能力；催化剂的活性稳定是保证加氢效果的前提；床层设计的处理能力限制是造成目前加氢效果 下降生产能力受限的主要原因。 关键词：a．甲基苯乙烯；滴流床反应器；加氢；影响因素 中图分类号：O 625．11 文献标志码：A 文章编号：1000—6613(2012)05—1173—05 Influence factors analysis of a-methyl styrene hydrOgenati0n reaction in a trickle—bed reactor DINGHengyang (BeijingYanshan Petrochemical Company Chemical Plant Three，Beijing 102500，China) Abstract：With 6c-MS，hydrogen as raw material，cumene was synthesized by catalytic hydrogenation in a trickle—bed．The work mainly investigated the influence of reaction temperature，pressure， circulation，feeding a—MS concentration，hydrogen Oi1 ratio on hydrogenation reaction．The results showed that the reaction temperature can accelerate the reaction rate within the range of 60—120 ℃： hydrogenation reaction rate is the fastest with the pressure from 0．7 to O．8MPa，processing capability is the largest；the improvement on hydrogen to oil ratio ensure raw materials and catalyst contact time under the premise of the reaction；the circulation rate and the concentration of the feed 一MS reaction rate can be changed but the actual processing capacity cannot be changed；the stability of catalytic activity is the premise of the hydr