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Porphyrin-Embedded Silicate Materials for Detection of Hydrocarbon Solvents 英文参考文献
Sensors 2011, 11, 886-904; doi:10.3390/s110100886
OPEN ACCESS
sensors
ISSN 1424-8220
/journal/sensors
Article
Porphyrin-Embedded Silicate Materials for Detection of
Hydrocarbon Solvents
Brandy J. Johnson *, Nicole E. Anderson, Paul T. Charles, Anthony P. Malanoski,
Brian J. Melde, Mansoor Nasir and Jeffrey R. Deschamps
Center for Bio/Molecular Science and Engineering, Naval Research Laboratory, Washington, DC
20375, USA; E-Mails: nanders2@ (N.E.A); paul.charles@ (P.T.C.);
anthony.malanoski@ (A.P.M.); brian.melde@ (B.J.M.);
mansoor.nasir@ (M.N.); jeff.deschamps@ (J.R.D.)
* Author to whom correspondence should be addressed; E-Mail: brandy.white@;
Tel.: +1-202-404-6100; Fax: +1-202-767-9598.
Received: 1 December 2010; in revised form: 5 January 2011 / Accepted: 13 January 2011 /
Published: 14 January 2011
Abstract: The development of porphyrin-embedded mesoporous organosilicate materials
for application to the detection of volatile hydrocarbon solvents is described. Design of the
receptor and optical indicator construct begins with parallel selection of the porphyrin
indicator and design of the mesoporous sorbent. For the porphyrin indicator, high binding
affinity and strong changes in spectrophotometric character upon target interaction are
desired. The sorbent should provide high target binding capacity and rapid binding
kinetics. A number of porphyrin/metalloporphyrin variants and organosilicate sorbents
were evaluated to determine the characteristics of their interaction with the targets,
benzene, toluene, and hexane. The selected porphyrin candidates were covalently
immobilized within a benzene-bridged sorbent. This construct was applied to the detection
of targets using both fluorescence- and reflectance-based protocols. The use of red, green,
and blue (RGB) color values from the constructs in a highly simplified detection scheme is
described.
Keywords: mesoporous; organosili
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