Selective Grafting of Primary Amines onto Carbon Nanotubes via Free-Radical Treatment in Microwave Plasma Post-Discharge 英文参考文献.docVIP

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Selective Grafting of Primary Amines onto Carbon Nanotubes via Free-Radical Treatment in Microwave Plasma Post-Discharge 英文参考文献.doc

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Selective Grafting of Primary Amines onto Carbon Nanotubes via Free-Radical Treatment in Microwave Plasma Post-Discharge 英文参考文献

Polymers 2012, 4, 296-315; doi:10.3390/polym4010296 OPEN ACCESS polymers ISSN 2073-4360 /journal/polymers Article Selective Grafting of Primary Amines onto Carbon Nanotubes via Free-Radical Treatment in Microwave Plasma Post-Discharge Benoit Ruelle 1,*, Sophie Peeterbroeck 1, Thomas Godfroid 1, Carla Bittencourt 2, Michel Hecq 1,2, Rony Snyders 1,2 and Philippe Dubois 1,2, * 1 Center of Innovation and Research in Materials Polymers (CIRMAP), Materia Nova Research Center, Parc Initialis, Avenue, N. Copernic 1, B-7000 Mons, Belgium; E-Mails: sophie.peeterbroeck@materianova.be (S.P.); thomas.godfroid@materianova.be (T.G.); Center of Innovation and Research in Materials Polymers (CIRMAP), University of Mons, Place du Parc 20, B-7000 Mons, Belgium; E-Mails: carla.bittencourt@umons.ac.be (C.B.); michel.hecq@umons.ac.be (M.H.); rony.snyders@umons.ac.be (R.S.) 2 * Authors to whom correspondence should be addressed; E-Mails: benoit.ruelle@materianova.be (B.R.); philippe.dubois@umons.ac.be (P.D.); Tel.: +32-65-554-976; Fax: +32-65-373-484. Received: 1 December 2011; in revised form: 6 January 2012 / Accepted: 10 January 2012 / Published: 30 January 2012 Abstract: A novel strategy to graft functional groups at the surface of carbon nanotubes (CNTs) is discussed. Aiming at grafting nitrogen containing groups, and more specifically primary amine covalent functionalization, CNTs were exposed under atomic nitrogen flow arising from an Ar + N2 microwave plasma. The primary amine functions were identified and quantified through chemical derivatization with 4-(trifluoromethyl)benzaldehyde and characterized through X-ray photoelectron spectroscopy. The increase of the selectivity in the primary amines grafting onto CNTs, up to 66.7% for treatment of CNT powder, was performed via the reduction of post-treatment oxygen contamination and the addition of hydrogen in the experimental set-up, more particularly in the plasma post-discharge c