Sequential solvent extraction for the modes of occurrence of selenium in coals of different ranks from the Huaibei Coalfield, China 英文参考文献.docVIP

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Sequential solvent extraction for the modes of occurrence of selenium in coals of different ranks from the Huaibei Coalfield, China 英文参考文献.doc

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Sequential solvent extraction for the modes of occurrence of selenium in coals of different ranks from the Huaibei Coalfield, China 英文参考文献

Geochemical Transactions BioMedCentral Research article Open Access Sequential solvent extraction for the modes of occurrence of selenium in coals of different ranks from the Huaibei Coalfield, China Ying Zhang1, Guijian Liu*1, Chen-Lin Chou2, Lei Wang1 and Yu Kang1 Address: 1CAS Key Laboratory of Crust-Mantle Materials and the Environment, School of Earth and Space Sciences, University of Science and Technology of China, Hefei 230026, China and 2Illinois State Geological Survey (Emeritus), Champaign, IL 61820, USA Email: Ying Zhang - gjl0607@163.com; Guijian Liu* - yangpy@; Chen-Lin Chou - chenlinchou@; Lei Wang - wl163@163.com; Yu Kang - lgj@ * Corresponding author Published: 20 December 2007 Received: 27 August 2007 Accepted: 20 December 2007 Geochemical Transactions 2007, 8:14 doi:10.1186/1467-4866-8-14 This article is available from: /content/8/1/14 ? 2007 Zhang et al; licensee BioMed Central Ltd. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Abstract Forms of selenium in bituminous coal, anthracite, and cokeite (natural coke) from Huaibei Coalfield, Anhui, China, have been determined by sequential solvent extraction. The selenium content in bulk samples is 4.0, 2.4, and 2.0 μg/g in bituminous coal, anthracite, and cokeite, respectively. The six forms of selenium determined by six-step solvent extraction are water- leachable, ion-exchangeable, organic matter-associated, carbonate-associated, silicate-associated, and sulfide-associated. The predominant forms of selenium in bituminous coal are organic matter- associated (39.0%), sulfide-associated (21.1%), and silicate bound (31.8%); these three forms account for 92% of the total. The organic matter bound-selenium decrease drama