Sulfur Bridged Multidentate Ligands Based on (Bi)pyridyl-(Bi)-1,3,4-Thiadiazolyl Conjugates 英文参考文献.docVIP

Molecules 2003, 8, 310-317 molecules ISSN 1420-3049 / Sulfur Bridged Multidentate Ligands Based on (Bi)pyridyl-(Bi)- 1,3,4-Thiadiazolyl Conjugates Antonino Mamo 1 *, Andrea Pappalardo and M. Teresa Clasadonte 1 2 1 2 Department of Physical and Chemical Methodologies for Engineering, Engineering Faculty, University of Catania, V.le Andrea Doria 6, I-95125 Catania, Italy. Tel.: (+39)-95-7382756, Fax: (+39)-95-33323. Department of Economy and Territory, Economy Faculty, University of Catania, Cso Italia 55, I- 95129 Catania, Italy. * Author to whom correspondence should be addressed; e-mail: mamo@dmfci.ing.unict.it Received: 22 January 2003; in revised form: 14 March 2003 / Accepted: 17 March 2003 / Published: 31 March 2003 Abstract: The synthesis of a series of mixed (bi)pyridyl/(bi)1,3,4-thiadiazolyl ligands, derived from the condensation of 2-mercapto-5-methylthio-1,3,4-thiadiazole or 5- mercapto-5-methylthio-2,2-bi-1,3,4-thiadiazole with 2,6-bis(chloromethyl)pyridine or 6,6’-bis(chloromethyl)-2,2’-bipyridine (compounds L1–L4), and of 2,5-dimercapto-1,3,4- thiadiazole or 5,5-dimercapto-2,2-di-1,3,4-thiadiazole with picolyl chloride hydrochloride or 6-chloromethyl-6-methyl-2,2-bipyridine (compounds L5–L8) in the presence of triethylamine is described. All new compounds have been characterized by FAB (+) spectrometry and NMR spectroscopy. C-NMR spectra are crucial to firmly establish the 13 thiol structure of the title ligands. Keywords: (Bi)pyridyl derivatives, (bi)-1,3,4-thiadiazolyl derivatives, (bi)pyridyl/(bi)- 1,3,4-thiadiazolyl mixed ligands, azathio ligands.  Molecules 2003, 8 311 Introduction It is well known that luminescent and redox active polypyridine-type metal complexes are playing a key role as molecular components in the development of supramolecular species capabl