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加拿大地表水检测限.pdf

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加拿大地表水检测限

Chemosphere 86 (2012) 565–571 Contents lists available at SciVerse ScienceDirect Chemosphere journal homepage: www.elsevier .com/locate/chemosphere Detection limits can inﬂuence the interpretation of pesticide monitoring data in Canadian surface waters Shane R. de Solla a,⇑, John Struger b, Tana V. McDaniel b a Wildlife and Landscape Science Directorate, Environment Canada, Canada Centre for Inland Waters, 867 Lakeshore Road, Burlington, Ontario, Canada L7R 4A6 b Water Science and Technology Directorate, Environment Canada, Canada Centre for Inland Waters, 867 Lakeshore Road, Burlington, Ontario, Canada L7R 4A6 a r t i c l e i n f o a b s t r a c t Article history: Water quality monitoring programs rely on residue data that are frequently left censored, due to some Received 11 May 2011 observations occurring below the Method Detection Limit (MDL). Our objective was to determine the Received in revised form 16 September inﬂuence the MDL has on the interpretation of pesticide residues in surface waters. Water samples from 2011 tributaries in southern and central Ontario were collected by Environment Canada from 2003 to 2008 and Accepted 20 September 2011 1 1 Available online 2 December 2011 were analyzed for 27 pesticides, with MDLs that averaged 7.02 ng L (range 0.39–25.1 ng L). We then simulated MDLs ranging from 25