Asymmetric Construction of All-Carbon Quaternary Stereocenters by Chiral-Auxiliary-Mediated Claisen Rearrangement and Total Synthesis of (+)-Bakuchiol.docVIP

Molecules 2012, 17, 13330-13344; doi:10.3390/molecules171113330 OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Asymmetric Construction of All-Carbon Quaternary Stereocenters by Chiral-Auxiliary-Mediated Claisen Rearrangement and Total Synthesis of (+)-Bakuchiol Ken-ichi Takao *, Shu Sakamoto, Marianne Ayaka Touati, Yusuke Kusakawa and Kin-ichi Tadano * Department of Applied Chemistry, Keio University, Hiyoshi, Kohoku-ku, Yokohama 223-8522, Japan * Authors to whom correspondence should be addressed; E-Mails: takao@applc.keio.ac.jp (K.T.); tadano@applc.keio.ac.jp (K.T.); Te