Experimental determination of the hydrothermal solubility of ReS2 and the Re–ReO2 buffer assemblage and transport of rhenium under supercritical conditions.docVIP

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Experimental determination of the hydrothermal solubility of ReS2 and the Re–ReO2 buffer assemblage and transport of rhenium under supercritical conditions.doc

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Experimental determination of the hydrothermal solubility of ReS2 and the Re–ReO2 buffer assemblage and transport of rhenium under supercritical conditions

Experimentaldeterminationofthehydrothermalsolubilityof ReS2andtheRe–ReO2bufferassemblageandtransportof rheniumundersupercriticalconditions YongliangXiong*aandScottA.Wood*b aDepartmentofGeologicalSciences,Rutgers,The StateUniversityofNewJersey, 610Taylor bDe I R oy D83844-3022,USA.E-mail:swood@uidaho.edu o f a G d e , P i s g c i a c t a a l w S a c y , N J s 0 , 8 U 8 5 n 4 - 8 0 s 6 6 , U S I A d . a E - , m B a o i l x : x 4 i 4 o 3 n 0 g 2 y 2 l @ r c i .r u t g e ,Moscow, r s .e d u Article p a r t m e n t o l o i e n c e i v e r i t o f h o Received4thOctober2001,Accepted17thDecember2001 PublishedontheWeb11thJanuary2002 FirstpublishedasanAdvancedArticleonthe web25thAugust2000 To understand the aqueous species important for transport of rhenium under supercritical conditions, we conducted a series of solubility experiments on the Re–ReO2 buffer assemblage and ReS2. In these experiments, pH was buffered by the K–feldspar–muscovite–quartz assemblage;fO in sulfur-free systems was buffered by the 2 Re–ReO2 assemblage; andfO andfS in sulfur-containing systems were buffered by the magnetite–pyrite– 2 2 pyrrhotite assemblage. Our experimental studies indicate that the species ReCl40 is dominant at 400uC in slightly acidic to near-neutral, and chloride-rich (total chloride concentrations ranging from 0.5 to 1.0 M) environments, and ReCl3z may predominate at 500uC in a solution with total chloride concentrations ranging from 0.5 to 1.5 M. The results also demonstrate that the solubility of ReS2 is about two orders of magnitude less than that of ReO2. This ?nding not only suggests that ReS2 (or a ReS2 component in molybdenite) is the solubility-controlling phase in sulfur-containing, reducing environments but also implies that a mixing process involving an oxidized, rhenium-containing solution and a solution with reduced sulfur is one of the most effective mechanisms for deposition of rhenium. In analogy wit