氧在金属铀表面的初期动力学.pdfVIP

Vo l. 33 No.1 核化学与放射化学 第 33 卷第 l 期 2011 年 2 月 lournal of Nuclear and Radiochemistry Feb. 2011 文章编号:0253回9950( 2011 )01-0061-04 氧在金属铀表面的初期动力学 银陈1 ，李赣1 ，张志2 ，杨江荣1 1.表团物理与化学国家重点实验室，四川绵阳 621907 , 2. 中国工程物理研究院，四川绵阳 621900 摘要:为了获得氧与铀初期反应的动力学性质，实验利用表面吸附分析系统，采用微压 PVT 方法研究了 0% 在清洁铺表面的初期吸附反应行为，测量了饱和吸附量和反应概率。结果表明，氧的吸附量趋近一个极大值， 15 2 约 4.3 X 10 /cm • 粘附概率起初随吸附量增加缓慢减少g 氧在清洁铀表面迅速解离，与表团铀原子反应生成 氧化物.氧离子扩散通过氧化物层，继续与界面处的铀原子发生反应g 气体初期反应动力学进程依赖于表面反 应产物的组成和厚度变化对分子解离和离子扩散过程的影响。 关键词:铀;PVT; 吸附量z 粘附概率s 动力学 中图分类号:TL214.6 文献标志码:A Early国Stage Reaction Kioetics of O2 00 Uranium Surface YIN Chen1 , LI Gan1 , ZHANG Zhj2, YANG liang-rong1 1. National Key Laboratory for Surface Physics and Chemistry. Mianyang 621907 , China; 2. China Academy of Engineering Physics. P. O. Box 919(71) , Mianyang 621900. China Abstract: The saturation capacity and reaction probability of Oz adsorption on clean uranium surface have been quantitatively measured by low pressure PVT method , and their reactivity and kinetic property were obtained. The experimental results show that Oz exhibited the reaction characteristics of adsorbed gas amount(coverage) is approaching a maximum value , about 4. 3 X 1015 / cmz and reaction probability is decreasing with a rise in adsorbed gas amount. Oxygen molecule on the clean uranium is dissociated rapidly , reacted to form oxide with exterior uranium atom. Oxygen particles diffuse to pass through oxide layer and react with uranium atom at interface. The initial re