冷冻干燥法制备纳米Al_2O_3包覆W复合粉体.pdfVIP

学兔兔 第28卷第5期 粉末冶金技术 Vo1．28．NO．5 2010年 10月 Powder Metallurgy Technology Oct．2Ol0 冷冻干燥法制备纳 1203包覆w复合粉体 徐祥阳 席晓丽一 聂祚仁 王志宏 陈广磊 (北京工业大学材料科学与工程学院，北京 100024) 摘 要： 用冷冻干燥法合成了包覆型粉体，与传统方法相比，无需以纳米或微米级核颗粒为前提，过程简单， 成本低。以偏钨酸铵和硫酸铝为原料，经喷雾预冻、真空冷冻干燥获得W／A1混合盐冻干前驱体，分段还原得 到纳米 AI 0 包覆w的复合粉体。采用XRD、IR、SEM等测试技术分析了样品的物相组成、结构、形貌，探讨 了包覆结构的形成机理。结果表明：合成的包覆粉体是由40nm左右 A1 0 颗粒均匀的包覆在 1 m左右w 颗粒表面。包覆结构的形成过程分为三个阶段：w晶粒的形核生长，非晶铝氧化合物包覆层的形成，A1，0 的 非均匀形核生长。 关键词：冷冻干燥；包覆；A1，0 ；W A new method for preparation of nanosized Al2 O 3 coated W composites Xu Xiangyang，Xi Xiaoli，Nie Zuoren，W ang Zhihong，Chen Guanglei (College of Materials Science and Engineering，Beijing University of Technology，Beijing 100024，China) Abstract：Freeze drying method for preparation of coating powders is put forward，which doesn’t need a core particle at first compared with the conventional methods．Nano—sized AI2 O3 coated W composites were prepared via freeze— drying and multi—reducing of the mixture of aluminum sulphate and AMT．The phase compositions，structure and morphologies of the compositeswere investigated by XRD、IR、SEM． The formation mechanism of the coating composites was also studied．The results indicate that W powders in size of 1 have regular shape and are coated ． with uniform A12 O3nanoparticles in size of 40nm． The mechanism is suggested to be th