水热法合成不同形貌羟基磷灰石.pdfVIP

学兔兔 第 15卷第5期 粉末冶金材料科学与工程 2010年10月 、bl_15NO 5 M ateri n a1s Scie ce and Engineering of Powder Metallurgy Oct．2010 ． ．．．．．．．．． ．． ． ．．． ．．．．． ．．．． ．．． ． ． ． ． ． ． ． ． ． ． ． ． ． ． ．． ． ． ． ． ． ． ． ． ． ． ． ． ． ． ． ． ． ． — — 水热法合成不同形貌羟基磷灰石 宋江凤，刘 咏，张 莹 (中南大学 粉末冶金 家重点实验室，长沙 410083) 摘 要：羟基磷灰石由于具有良好的生物相容性和牛物活性而应用广泛，形貌控制对其应用全关重要。本文分别 以Ca(NO3)24H2O、KH2PO43H2O为Ca源和P源，采用水热法制备不同形貌的羟基磷灰石。用X射线衍射(XRD) 和扫描电镜(SEM)对反应产物进行表征，研究水热反应温度、水热反应时间和反应物浓度对羟基磷广火石形貌的影响。 结果表明，不同条件下，产物为长径比不同的片状、带状及花状羟基磷灰石(HA)，其长度为1～100 pm、宽l～5 um、 厚约100 am、长径比为1～100，并从晶体生长动力学方面探讨不同合成条件对羟基磷灰石形貌的影响机理。 关键词：羟基磷灰石：水热法：形貌控制：长径比 中图分类号：TF123．12 文献标识码：A 文章编号：1673—0224(2010)5—505—06 Hydr0xyapatite particles with different morphologies synthesized by hydrothermal method SONG Jiang—feng，LIU Yong，ZHANG Ying (State Key Laboratory ofPowder Metallurgy，Central South University，Changsha 410083，China) Abstract：Hydroxyapatite has been widely used because of its excellent biocompatibility and bioactivity，and the morphology control is of critical importance for its usage．In the present papeL hydroxyapatite particles with different morphologies were synthesized through hydrothermal method，using Ca(NO3)2’4H20 and KH2PO4’3H20 as the Ca and P sources，respectively．The effects of hydrothermal temperature，time and concentration of reactants as well on the morphology were studied．The products were charaterized by X—ray diffraction(XRD)and