甘油体系中纳米铜粉的制备研究.pdfVIP

学兔兔 第2O卷第 2期 粉 末 冶 金 工 业 Vo1．2O NO．2 2010年4月 P0WDER METALLURGY INDUSTRY Apr．2010 甘油体系中纳米铜粉的制备研究 王鸿显。吴飞飞，杨思维 (南通大学化学化工学院，江苏 南通 226007) 摘 要：本课题采用甘油还原铜盐法制备纳米铜粉。将甘油和铜盐按一定量的摩尔配比混合 加热，同时加入适量的分散剂PVP，快速搅拌，控温反应一定时间，冷却至室温，产品经无水乙 醇稀释后，再用无水乙醇数次洗涤、抽滤，398 K真空干燥2 h，得到紫色纳米铜粉。并对纳米 铜粉进行了XRD、TEM表征。结果表明：所制备的纳米铜粉呈球形，铜粉粒径小于60 nm，分 散性较好，纯度较高。 关键词：纳米铜粉；甘油；铜盐；表征分析 中图分类号：TQ622．2 3 文献标识码：A 文章编号：l006—6543(201O)02—0012—05 RESEARCH ON PREPARATION OF NAN0METER COPPER POWDER BY GLYCEROL PROCESS W ANG Hong-xian，WU Fei-fei。YANG Shi-wei (College of Chemistry and ChemicalEngineering，Nantong University，Nantong Jiangsu 226007，China) Abstract：The preparation of nanocrystalline copper powder involing reduced from copper salt by glycerol was studied．The salt was suspended in glycerol(AR grade)at an appropriate molar ratio between salt and glycerol with some PVP as dispersing agent．The suspension was heated and stirred for certain time and then was cooled to room temperature，and diluted with anhydrous alcoho1．The precipitated metal powder was washed using anhydrous alcohol as washing agent．The powder was dried in vacuum at 398 K for 2 h．The samples were stud— ied by TEM and XRD．The results showed that copper powder was pure，dispersive，spherical particles have a size lese than 60 nm． Key words：nanometer copper powder，glycerol，copper salt，characterization analysis 纳米铜粉由于其优异的电气性能，广泛应用于 相蒸汽法、等离子法、7射线辐照一水热结晶联合