钒掺杂TiO2粉体的制备及性能.pdfVIP

学兔兔 第 14卷第 l期 粉末冶金材料科学与工程 2009年2月 、b1．14 NO．1 Materials Science and Engineering of Powder Metallurgy Feb．2009 钒掺杂TiO2粉体的制备及性能 杨贞妮，刘 强，朱忠其，张 瑾，柳清菊 (云南大学 材料科学与工程系，昆明650091) 摘 要：严重的环境和能源问题推动了对以TiO2为主的半导体光催化材料的研究。金属阳离子掺杂TiO2，可以 有效地提高光催化材料对可见光的响应及光催化性能。该文作者采用水相法制备以不同比率掺杂钒的TiO2粉体， 并用H2SO 溶液浸渍处理，研究掺杂比率对粉体吸收光谱和光催化降解甲基橙的影响。结果表明：钒掺杂可以使 TiO2粉体的光波长响应阈值移至600 nm左右，大大提高了TiO2对可见光的吸收；钒的掺杂比率(摩尔分数)为2．5％ 时，粉体在普通日光灯下照射6 h，对甲基橙的降解率达到69％，高于纯TiO 粉体；硫酸修饰则提高了掺杂钒的 TjO，粉体的光催化性。 关键词：可见光催化：钒掺杂；TiO2；甲基橙降解 中图分类号：0643 文献标识码：A 文章编号：1673—0224(2009)1—63．04 Preparation and properties of V-doped TiO2 powders YANG Zhen·ni，LIU Qiang，ZHU Zhong-qi，ZHANG Jin，LIU Qing-ju (Department of Material Science and Engineering，Yunnan University，Kunming 65009 1，China) Abstract：Environmental pollution and energy resources shortening have prompted an enormous research in TiO2 semiconductor—based photocatalysts over the last decade．Doping of metal cations into TiO2 is attracting a continuously increasing attention because of its high reactivity under visible—light．In the present paper’S research，TiO2 powders doped with different concentration of vanadium were prepared by aqueous phase method，and the powders were infiltration treated in H2SO4 solution．The effects of doping concentration on the absorption spectrum and photocatalytic degradation of methyl orange were studied．The results indicate that the absorbing wavelength threshold value of V-doped TiO2 powders is shifted to about 600 nnl，and it largely enhances the Ti02 absorpt