LiNO3对活性集料碱-硅酸反应的抑制效果.pdfVIP

学兔兔 2013年第 9期(总第 287期 ) 混 凝 土 原材料及辅助物料 Number 9 in 2013(Total No．287) Concrete MATERIAI AND ADMINICLE doi：10．3969／j．issn．1002—3550．2013．09．019 LiNO3对活性集料碱一硅酸反应的抑制效果 李 根。邓 敏，莫立武 (南京工业大学 材料科学与工程学院材料化学工程国家重点实验室，江苏 南京 210009) 摘要：试验采用快速砂浆棒法和小混凝土柱法研究LiNO，对沸石化珍珠岩、防城港砂岩、锦屏砂岩和两河口砂岩四种集料ASR 膨胀的抑制效果。研究表明，对于沸石化珍珠岩，掺加锂盐对试件ASR膨胀有较好的抑制效果，但是当锂盐掺量不足时在后期膨 胀率甚至超过了未掺锂盐的试件。对于防城港砂岩，两种试验方法都表明，[Li]／[Na+K]摩尔比越大，试件的膨胀率越小。足量的 LiNO 对ASR膨胀的抑制效果越好。对于锦屏砂岩，[Li]／[Na+K]摩尔比越大，砂浆试件膨胀率越小。对于两河口砂岩，两组试验都 表明，掺加LiNO 的试件的膨胀率在后期都超过了未掺锂盐的试件；砂浆试件中[Li]／INa+K]=2．22时，在短龄期内才有一定的抑 制效果。 关键词：碱一硅酸反应；硝酸锂；砂浆棒；小混凝土柱 中图分类号： TU528．04 文献标志码： A 文章编号： 1002—3550(2013)09—0066—04 Effects of lithium nitrate on controlling ASR expansion of reactive aggregates L／Gen，DENGMin，MOLiwu (State Key Laboratory ofMaterials·Oriented Chemical Engineering，College ofMaterials Science an Engineering， NanjingUniversityofTechnology，N删ing210009，China) Abstract： Tests were carried out to determine the efficacy of LiNO3 on controlling expansion of mortar bars and microbars prepared with four alkali—silica reactive aggregates．Results showed that，for zeolitization perlite，specimens with LiN03 showed good inhibition effect in both tests；but while the content ofLiNO3 was insufficient，later expansion may even more than those ofno lithium specimen．For Fangchenggang sandstone，the results of this two methods showed that greater inhibition was caused with increasing molar ratio of[Li]／ 【Na+K]and enough content of LiNO3 was better fo