掺有超细矿渣粉的水泥砂浆的抗硫酸盐侵蚀性能.pdfVIP

学兔兔 2013年 第 5期 (总 第 283期 ) 混 凝 土 预 拌 砂 浆 Number 5 in 2013(Total No．283) Concrete READY MIXED M0RTAR doi：10．3969／j．issn．1002—3550．2013．05．036 掺有超细矿渣粉的水泥砂浆的抗硫酸盐侵蚀性能 郭书辉，潘志华，王学兵，张 俊 (南京工业大学 材料科学与工程学院，江苏 南京 210009) 摘 要： 硫酸盐侵蚀是影响混凝土耐久性的重要因素之一，对于海港或地下构筑物水泥混凝土的抗硫酸盐侵蚀能力尤其受到关 注。在试验室条件下研究了超细矿渣粉取代量为0(即参比样)、15％、25％Jk泥制成的水泥砂浆在不同浓度硫酸盐介质环境下的力学 性能变化，同时，借助于XRD对侵蚀试样的成分进行了分析。试验结果表明，15％和25％的超细矿渣粉的引入不仅可以增加水泥 砂浆的强度，而且可以提高其抗硫酸盐侵蚀性能；与参比样相比，掺有超细矿渣粉的水泥砂浆试样内部Ca(OH)：的量和钙矾石的 量明显减少，暗示超细矿渣粉与水泥水化放出的Ca(OH) 发生了化学反应。 关键词：超细矿渣粉；水泥砂浆；硫酸盐侵蚀；抗蚀系数 中图分类号： TU528．041 文献标志码：A 文章编号： 1002—3550(2013)05—0127—03 Resistance against sulfate a~ack of cement mortar blended with ultrafine slag powder GUOShu-hui，PANZhi-hua，WANGXue-bing，ZHANGJun (College ofMaterials Science andEngineering，NanjingUniversityofTechnology。Nanjing 210009，China) Abstract： Sulfate attack is one of the most important factors influencing the durability of cement concrete．It was especially taken atten— tion while cement concre~was used for constructions under sea water or underground．Change of the physical properties of the cement mortars prepared from Portland cement and those blended with 1 5％and 25％ ultrafine granulated blast—fumace slag exposed to different sulfate solution environment was investigated，and meanwhile，the composition of the exposed cement mortar specimens was also exam— ined by means of XRD analysis．Results showed that not only the strength of the mortar specimens blended with 15％ and 25％ ultrafine granulated blast-furnace slag increased but also their resistance against sulfate attack was improved as compared with those