改性萘系减水剂对水泥基材料性能的影响.pdfVIP

学兔兔 2011年第11期 混凝土与水泥制品 2011 Noll 11月 CHINA C0NCRETE AND CEMENT PRODUCTS November 改性萘系减水剂对水泥基材料性能的影响 赵 平，严 云，胡志华，王田堂 (四川省非金属复合与功能材料重点实验室一省部共建国家重点实验室培育基地， 西南科技大学，绵阳621010) 摘 要：用经氧化醚化等改性制得的氧化醚化淀粉(OES)与萘系减水剂复配改性，研究了改性萘系减水剂对水 泥基材料性能的影响。结果表明，改性萘系减水剂能有效改善萘系减水剂的保坍行为，使水泥浆体保持较长的塑化 时间，水泥水化诱导期明显延长；掺 13％改性萘系减水剂的水泥浆体2h坍落度损失仅为6％，远小于掺萘系减水剂 的56％；与掺萘系减水剂的水泥浆体相比，-3改性萘系减水剂中OES含量为5％-13％时，水泥净浆流动度2h损失减 小了17％-89％，28d水泥胶砂强度则相应提高了12％~20％。 关键字：萘系减水剂：改性萘系减水剂；流动度；空间位阻 Abstract：Through the complex formulation and modification between the naphthalene sulphonate superplasticizer and oxidative etherified starch fOES1 prepared by the oxidation and etherification treatment the effects of the modified naphthalene sulphonate superplastieizer on the performances of cementitious materials are studied．The results indicate that the modified naphthalene sulphonate superplasticizer can obviously improve the slump retaining of naphthalene sulphonate superplasticizer，the flowability of cement paste is effectively improved compared to ordinary naphthalene sulphonate superplasticizer and the hydration induction period can be prolonged obviously．The slump loss of cement paste with 1 3％ modified naphthalene sulphonate superplasticizer is only 6％ after 2 hours which is much lower than that of the ordinary naphthalene sulphonate superplastieizer．In comparison with cement paste added with naphthalene sulphonate superplasticizer．when the content of OES is 5％～1 3％．the flowability lOSS of cement paste after 2 hours reduces by 1 7％ 89％．and 28d compre