MPEG系高牲能减水剂分子结构对水泥颡粒分散牲的影响.pdfVIP

学兔兔 新癯建赡 中国科技核心期刊 MPEG系高牲能减水剂分子结构对 水泥颡粒分散牲的影晌 柯余良，张小芳，方云辉，林艳梅，郭鑫祺，林添兴，于飞宇 (科之杰新材料集团有限公司，福建 厦门 361100) 摘要：采用不同分子质量的MPEG合成出一系列聚羧酸系高性能减水剂，通过FT—IR、凝胶渗透色谱对其进行分子结构表征， 探讨了聚氧乙烯基(PEO)侧链长度及其接枝密度和聚合物分子质量对水泥颗粒分散性能的影响。结果表明，PEO侧链长度和侧链接 枝密度与水泥颗粒分散性密切相关；对于不同PEO侧链长度的减水剂，侧链接枝密度适中时，减水剂表现出较高的分散能力以及分 散性保持能力；聚合物分子质量不宜过大或过小，只有适中分子质量的减水剂产品才具有最佳的分散效果：较高的大单体转化率相 当于提高了聚羧酸产品的有效掺量，有利于提升聚羧酸减水剂的分散性能。 关键词：高性能减水剂；分子质量；侧链长度；接枝密度 中图分类号：TU56 文献标识码：A 文章编号：1001—702X(2014)02-0013—03 Effect of molecular structure of MPEG based high performance water reducing agent on the cement particle dispersibility KE Yuliang，ZHANG Xiaofang，MNG Yunhui，LIN Yanmei,GUo Xinqi，L Tianxing，YU (KzJ New Materials Group Co．Ltd．，Xiamen 361 100，Fujian，China) Abstract：A series of polyearboxylate water reducers(PCs)were synthesized with different molecular MPEG．The molecular structure of PCs wag characterized by FT—IR and gel permeation chromatography．The effect of polyethylene oxide(PEO)side chain length，the grafting density and polymer molecular weight on the dispersibility of the cement particles was discussed．The results show that the PEO side chain length and the grafting density is closely related to the cement particle dispersibility．The PCs with a moderate polyethylene oxide(PEO)side chain exhibit a higher dispersibility and dispersion stability．Only PCs with a moderate molecular weight show the optimum dispersible effect．Hi sher monomer conversion