早强型聚羧酸高性能减水剂的合成研究.pdfVIP

学兔兔 杆 蟓粉 中国科技核心期刊 早强型聚羧酸高胜雒濂水剂的合成研究 林艳梅 (科之杰新材料集团有限公司，福建 厦门 361100) 摘要：由马来酸酐与三乙醇胺酯化后得到的产物(P1)，再与丙烯酸(AA)、异丁烯醇聚氧乙烯醚(HPEG)共聚得到一种早强型聚 羧酸减水剂。实验结果表明：当 【马来酸酐(MAn)】：n[三乙醇胺(rrEA)】=l_1：1．0，自制固体催化剂用量为马来酸酐质量的O．4％，在 llO℃下反应4h，可得到酯化率较高的酰胺单体P1；共聚时，当re(P1)：m(丙烯酸)：m(双氧水)：m(巯基乙酸)=4．8：19．7：2．2：1．0，合成 减水剂的早强性能最佳。该产品折固掺量为O．2％时，按GB 8076--2008进行性能测试，1 d抗压强度比高达198％，同时其它各项性 能指标均符合高性能减水剂的要求。 关键词：酯化；早期强度；聚羧酸高性能减水剂；合成研究 中图分类号：TU528．042．2 文献标识码：A 文章编号：10o1—702X(2014)05—00l1—04 Synthesize and performance on early-type of high-perform ance polycarboxylate superlasticizer LIN Yanmei (KzJ New Materials Group Co．Ltd．，Xiamen 361100，Fujian，China) Abstact：An early-type of hish-performance polycarboxylate superlasticizer was synthesized by using an ether macromonomer， erylie acid(AA)and a monomer(P1)，which was synthesized by using maleie anhydride and triethanolamine．Experiment results show that product obtained optimum when the maleic anhydride and triethanolamine molar ratio was 1．1：1．0，catalyst for the acylation Was 0．4％ of the lllass of maleic anhydride，reaction for 4h at 110 oC．When the ratio of P1，AA，H202 and mercaptoacetic acid Was 4．8：19．7：2．2：1．0，the early strength performance of the product was the best．According to GB 8076--2008，when the solid content of the product Was O．2％，1 d compressive s~ength ratio was as hish as 198％，and other variousindexes meet the requirements of high performance water reducing agent． Key words：esterification；early strength：hish performance polycarboxylate superlastieizer；synthesis research 聚羧酸减水剂作为新型的高性能