超高浓度聚羧酸系减水剂的制备研究.pdfVIP

学兔兔 钎 建蟓 中国科技核心期刊 超高浓度聚羧酸系减水剂的制备研究 蒋卓君，方云辉，郭鑫祺，林添兴，官梦芹，尤仁良 (科之杰新材料集团有限公司，福建 厦门 361101) 摘要：通过实验对反应温度、反应时间、链转移剂、引发体系等因素对超高浓度聚羧酸系减水剂分散性能的影响进行了研究。 结果表明，使用维生素C一双氧水氧化还原引发体系 (H 02)：n(Vc)=4：l】，H20 用量为大单体的1．5％，磷酸三钠用量为大单体的 1．2％，SMAs用量为大单体的6％，在室温(20～40℃)条件下反应3 h，合成的超高浓度(质量浓度80％)聚羧酸系减水剂的分散性能 优良。当减水剂折固掺量为0．20％、水灰比为0．29时，水泥净浆流动度可达285 nnn，60min净浆流动度为288mm，120min净浆流 动度为282 mill，流动度经时损失小；同时其混凝土应用性能良好，减水率达30％。 关键词：超高浓度；聚羧酸减水剂；合成；性能 中图分类号：TU528．042．2 文献标识码：A 文章编号：1001—702X(2013)03—0029—03 Preparation of an extra high-concentration polyearboxylate superplasticizer JIANC Zhuojun，FANG Yunhui，GUO Xinqi，LIN Tianxing，GUAN Mengqin，YOU Renliang (Fujian Prominent Science New Materials Co．Ltd．，Xiamen 361101，Fujian，China) Abstract：Through experiments，the influence of reaction temperature and time，chain—transfer agent and initiator systems on the dispersivity performance of the extra high-concentration polycarboxylate superplasticizer was researched．The results indicated that the optimal reaction conditions were as follows：H202：Vc=4：1(redox initiator system)，1．5％ dosage of hydrogen peroxide(mass of maeromonomer)，l-2％ dosage of sodium phosphate(mass of macromonomer，used as a chain transfer agent)，6％ dosage of SMAS (mass of macromonomer)，at room temperature(20,--40℃)for 3 h，which can synthesize a high-performance polycarboxylate super— plasticizer with extra high concentration(8O％)．When O．20％ dosage(converted into solid)of superplasticizer and O．29 of W／C，the net paste fluidity can reach up to 285 inln，60 min net paste fluidity can be 288 nun，and 120 min net paste fluidity can be 282 mI