较大偏高岭土掺量下水泥基材料的水化和性能.pdfVIP

第 18卷第5期 建 筑 材 料 学 报 VoI．18。No．5 学兔兔 2015年1O月 JOURNAL OF BUILDING MATERIALS Oct．，2015 文章编号：1007—9629(2015)05—0757—06 较大偏高岭土掺量下水泥基材料的水化和性能 乔春雨 倪 文， 王长龙 (北京科技大学金属矿山高效开采与安全教育部重点实验室，北京100083) 摘要：测定了较大偏高岭土(MK)掺量下偏高岭土一水泥(MK-C)砂浆的抗压强度、MK-C净浆的水 泥相对水化程度和累计放热量，探讨了净浆化学结合水量，砂浆抗压强度与净浆累计放热量的关 系．结果表明：考虑了“稀释效应”、MK表面成核效应及火山灰效应的有效接触表面积模型可定量 表征 MK—C砂浆的抗压强度；水泥相对水化程度随MK掺量的增加而逐渐增大，随龄期的延长而 先增加后降低；随MK掺量的增加，净浆最大累计放热量逐渐降低，最大累计放热增量逐渐变大， 净浆化学结合水量与累计放热量在养护早期和后期存在不同的线性关系，砂浆早期抗压强度与净 浆累计放热量线性相关． 关键词：偏高岭土；强度；相对水化程度；水化热；表面成核效应；火山灰反应 中图分类号：TU528．0 文献标志码：A doi：10．3969／j．issn．1007-9629．2015．05．007 Hydration and Mechanical Properties of Cement-Based Materials with High Use Level of Metakaolin QIAO Chunyu， NI肌 ， WANG Changlong (Key Laboratory of the Ministry of Education of China for High-Efficient Mining and Safety of Metal Mines，University of Science and Technology Beijing，Beijing 100083，China) Abstract：To study the relations between the mechanical properties and hydration of cement-based materials with high use level of metakaolin(MK)，compressive strength of metakaolin-cement(MK—C)mortars and the relative hydration degree of cement in MK—C pastes as well as hydration heat were measured．The relations between non-evaporable water amount，compressive strength and hydration heat were also investigated．Re— sults show that compressive strength of MK—C mortars can be quantified by the effective contact surface mod— el，in which the dilution effect，the heterogeneous nucleation effect and the pozzolanic reaction are all taken in- to consideration．T